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Dichlorido(methanol-?O)[2-(2-pyridyl-meth-oxy)-1,10-phenanthroline-?N,N',N'']manganese(II).

ABSTRACT: In the title mononuclear complex, [MnCl(2)(C(18)H(13)N(3)O)(CH(4)O)], the Mn(II) ion assumes a distorted octa-hedral geometry. There is a ?-? stacking inter-action between the phenanthroline ligand and the pyridine ring of a neighboring complex [centroid-to-centroid distance 3.5518?(13)?Å]. The crystal structure also contains weak inter-molecular O-H?Cl hydrogen bonds that link neighboring complex mol-ecules into a one-dimensional chain along the b axis.

SUBMITTER: Li HL

PROVIDER: S-EPMC2961758 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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Dichlorido(methanol-κO)[2-(2-pyridyl-meth-oxy)-1,10-phenanthroline-κN,N',N'']manganese(II).

Li Hong Liang HL Chao Hou H

Acta crystallographica. Section E, Structure reports online 20080625 Pt 7

In the title mononuclear complex, [MnCl(2)(C(18)H(13)N(3)O)(CH(4)O)], the Mn(II) ion assumes a distorted octa-hedral geometry. There is a π-π stacking inter-action between the phenanthroline ligand and the pyridine ring of a neighboring complex [centroid-to-centroid distance 3.5518 (13) Å]. The crystal structure also contains weak inter-molecular O-H⋯Cl hydrogen bonds that link neighboring complex mol-ecules into a one-dimensional chain along the b axis. ...[more]

PMID: 21202809

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Dichlorido(2-meth-oxy-1,10-phenanthroline-?N,N')zinc(II).

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