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[N-(3-Meth-oxy-2-oxidobenzyl-idene-?O)leucinato-?N,O](1,10-phenanthroline-?N,N')copper(II) monohydrate.

ABSTRACT: The asymmetric unit of the title complex, [Cu(C(14)H(17)NO(4))(C(12)H(8)N(2))]·H(2)O, contains two independent Cu(II) complex mol-ecules and two uncoordinated water mol-ecules. In each complex mol-ecule, the Cu atom is O,N,O'-chelated by the tridentate Schiff base ligand and N,N'-chelated by the 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. The Cu-N bond distances in the apical directions are 2.298?(4) and 2.268?(4)?Å. In the crystal, inter-molecular O-H?O and C-H?O hydrogen bonds together with C-H?? inter-actions result in a three-dimensional supra-molecular structure.

SUBMITTER: Huang L

PROVIDER: S-EPMC3011713 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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[N-(3-Meth-oxy-2-oxidobenzyl-idene-κO)leucinato-κN,O](1,10-phenanthroline-κN,N')copper(II) monohydrate.

Huang Lei L Dong Jianfang J Jing Buqin B Li Lianzhi L Wang Daqi D

Acta crystallographica. Section E, Structure reports online 20101113 Pt 12

The asymmetric unit of the title complex, [Cu(C(14)H(17)NO(4))(C(12)H(8)N(2))]·H(2)O, contains two independent Cu(II) complex mol-ecules and two uncoordinated water mol-ecules. In each complex mol-ecule, the Cu atom is O,N,O'-chelated by the tridentate Schiff base ligand and N,N'-chelated by the 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. The Cu-N bond distances in the apical directions are 2.298 (4) and 2.268 (4) Å. In the crystal, inter-molecular O-H⋯O and C-H⋯O hydrog ...[more]

PMID: 21589245

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