Unknown

Dataset Information

0

7,8,9,10-Tetra-hydro-2-methyl-cyclo-hepta-[b]indol-6(5H)-one.

ABSTRACT: The title compound, C(14)H(15)NO, was synthesized from 2-hydroxy-methyl-enecyclo-hepta-none via a Japp-Klingemann acid-catalyzed cyclization. The seven-membered ring exhibits a slightly distorted envelope conformation. N-H?O hydrogen bonds form a centrosymmetric dimer; C-H?O hydrogen bonds and ?-? stacking inter-actions (the centers of the atoms involved in the stacking interaction are separated by 3.504?Å) give rise to another type of centrosymmetric dimer. In combination, these inter-actions create a stair-like chain of mol-ecules that inter-acts only loosely with neighboring chains via van der Waals inter-actions and weak C-H?? contacts.

SUBMITTER: Sridharan M 

PROVIDER: S-EPMC2961774 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

7,8,9,10-Tetra-hydro-2-methyl-cyclo-hepta-[b]indol-6(5H)-one.

Sridharan Makuteswaran M   Prasad Karnam J Rajendra KJ   Ngendahimana Aimable A   Zeller Matthias M  

Acta crystallographica. Section E, Structure reports online 20080607 Pt 7

The title compound, C(14)H(15)NO, was synthesized from 2-hydroxy-methyl-enecyclo-hepta-none via a Japp-Klingemann acid-catalyzed cyclization. The seven-membered ring exhibits a slightly distorted envelope conformation. N-H⋯O hydrogen bonds form a centrosymmetric dimer; C-H⋯O hydrogen bonds and π-π stacking inter-actions (the centers of the atoms involved in the stacking interaction are separated by 3.504 Å) give rise to another type of centrosymmetric dimer. In combination, these inter-actions c  ...[more]

Similar Datasets

Unknown 4-Methyl-7,8,9,10-tetra-hydro-cyclo-hepta-[b]indol-6(5H)-one.
| S-EPMC2968932 | biostudies-literature
Unknown 7,8,9,10-Tetra-hydro-cyclo-hepta-[b]indol-6(5H)-one.
| S-EPMC2960645 | biostudies-literature
Unknown 2,5-Dimethyl-7,8,9,10-tetra-hydro-cyclo-hepta-[b]indol-6(5H)-one.
| S-EPMC3009033 | biostudies-literature
Unknown 2-Chloro-7,8,9,10-tetra-hydro-cyclo-hepta-[b]indol-6(5H)-one.
| S-EPMC3379447 | biostudies-literature
Unknown 5-Methyl-7,8,9,10-tetra-hydro-cyclo-hepta-[b]indol-6(5H)-one.
| S-EPMC3120537 | biostudies-other
Unknown 2-Acetyl-3,5,5,9-tetra-methyl-6,7,8,9-tetra-hydro-5H-benzocyclo-hepten-7-one.
| S-EPMC3050136 | biostudies-literature
Unknown 2-(4-Bromo-phen-yl)-4-(4-meth-oxy-phen-yl)-6,7,8,9-tetra-hydro-5H-cyclo-hepta-[b]pyridine.
| S-EPMC3685096 | biostudies-literature
Unknown 5-Methyl-1,2,3,3a-tetra-hydro-benzo[e]pyrrolo-[2,1-b][1,3]oxazepin-10(5H)-one.
| S-EPMC3213428 | biostudies-literature
Unknown 2-[2-(Methyl-amino)-benzo-yl]-2,3,4,9-tetra-hydro-1H-pyrido[3,4-b]indol-1-one.
| S-EPMC2979469 | biostudies-literature
Unknown Crystal structure of 2-benzyl-amino-4-(4-meth-oxy-phen-yl)-6,7,8,9-tetra-hydro-5H-cyclo-hepta-[b]pyridine-3-carbo-nitrile.
| S-EPMC4257429 | biostudies-literature