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Bis(μ-N-benzyl-N-methyl-dithio-carbamato)-1:2κS,S':S';1:2κS:S,S'-bis-[bis-(N-benzyl-N-methyl-dithio-carbamato-κS,S')thallium(III)].

ABSTRACT: The molecule of the dinuclear title compound, [Tl(2)(C(9)H(10)NS(2))(6)], possesses a crystallographically imposed centre of symmetry. Each Tl(III) atom is seven-coordinated by S atoms of four different dithio-carbamate anions in a distorted penta-gonal-bipyramidal coordination geometry. The crystal structure is stabilized by a C-H⋯S hydrogen-bond inter-action linking complex mol-ecules into chains running parallel to the b axis. Intramolecular C-H⋯S hydrogen bonds are also present.

SUBMITTER: Rizzoli C 

PROVIDER: S-EPMC2961943 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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Bis(μ-N-benzyl-N-methyl-dithio-carbamato)-1:2κS,S':S';1:2κS:S,S'-bis-[bis-(N-benzyl-N-methyl-dithio-carbamato-κS,S')thallium(III)].

Rizzoli Corrado C   Ramalingam Kuppukkannu K   Alexander Nagarajan N  

Acta crystallographica. Section E, Structure reports online 20080712 Pt 8

The molecule of the dinuclear title compound, [Tl(2)(C(9)H(10)NS(2))(6)], possesses a crystallographically imposed centre of symmetry. Each Tl(III) atom is seven-coordinated by S atoms of four different dithio-carbamate anions in a distorted penta-gonal-bipyramidal coordination geometry. The crystal structure is stabilized by a C-H⋯S hydrogen-bond inter-action linking complex mol-ecules into chains running parallel to the b axis. Intramolecular C-H⋯S hydrogen bonds are also present. ...[more]

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