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(?-4,4'-Bipyridine-?N:N')bis-[bis-(N,N-dimethyl-dithio-carbamato-?S,S')zinc(II)].

ABSTRACT: The title dinuclear Zn(II) complex, [Zn(2)(C(3)H(6)NS(2))(4)(C(10)H(8)N(2))], is centrosymmetric; the mid-point of the C-C bond linking the two pyridine rings is located on an inversion center. The pyridine N atom coordinates to the Zn(II) cation, which is also chelated by two dimethyl-dithio-carbamate anions, giving a trigonal-bipyramidal ZnNS(4) geometry. Weak inter-molecular C-H?S hydrogen bonding is present in the crystal structure.

SUBMITTER: Zha MQ

PROVIDER: S-EPMC3009053 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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(μ-4,4'-Bipyridine-κN:N')bis-[bis-(N,N-dimethyl-dithio-carbamato-κS,S')zinc(II)].

Zha Mei-Qin MQ Li Xing X Bing Yue Y Lu Yue Y

Acta crystallographica. Section E, Structure reports online 20101023 Pt 11

The title dinuclear Zn(II) complex, [Zn(2)(C(3)H(6)NS(2))(4)(C(10)H(8)N(2))], is centrosymmetric; the mid-point of the C-C bond linking the two pyridine rings is located on an inversion center. The pyridine N atom coordinates to the Zn(II) cation, which is also chelated by two dimethyl-dithio-carbamate anions, giving a trigonal-bipyramidal ZnNS(4) geometry. Weak inter-molecular C-H⋯S hydrogen bonding is present in the crystal structure. ...[more]

PMID: 21588882

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