Browse
Submit Data
Databases
API
Help

Dataset Information

7 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis{2-bromo-4-chloro-6-[2-(phenyl-sulfon-yl)hydrazonometh-yl]phenolato-κN,O}copper(II).

ABSTRACT: The Cu atom in the title compound, [Cu(C(13)H(9)BrClN(2)O(3)S)(2)], is chelated by two deprotonated Schiff base ligands in a square-planar coordination geometry; the Cu atom lies on a center of inversion. The -NH- group of one anion forms an intra-molecular hydrogen bond to the phenolate atom of the symmetry-related ion.

SUBMITTER: Yusnita J

PROVIDER: S-EPMC2961959 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Bis{(E)-4-bromo-2-[(2-chloro-3-pyrid-yl)imino-meth-yl]phenolato-?N,O}copper(II).

Project description:In the title complex, [Cu(C(12)H(7)BrClN(2)O)(2)], the Cu(II) center is tetra-coordinated by two phenolate O and two azomethine N atoms from two independent bidentate 4-bromo-2-[(2-chloro-3-pyrid-yl)imino-meth-yl]phenolate (L) ligands. In the crystal structure, the Cu(II) atom has a distorted square-planar coordination environment. The inter-planar dihedral angles between the benzene and pyridine rings in the individual ligands are 63.83?(4) and 54.43?(3)°, indicating the pyridine ring to have considerably weaker steric hindrance.

| S-EPMC2977463 | biostudies-literature

Bis[4-chloro-2-(imino-meth-yl)phenolato]copper(II).

Project description:In the title mononuclear copper(II) complex, [Cu(C(7)H(5)ClNO)(2)], the Cu atom, situated on an inversion center, is four-coordinated, in a slightly distorted square-planar geometry, by the N- and O-donor atoms of two symmetry-related 4-chloro-2-(imino-meth-yl)phenolate Schiff base ligands.

| S-EPMC2968960 | biostudies-literature

Bis{6-bromo-4-chloro-2-[(E)-(2-chloro-phenyl)-imino-meth-yl]-phenolato-?(2)N,O}copper(II).

Project description:In the title compound, [Cu(C(13)H(7)BrCl(2)NO)(2)], or CuL(2) {where HL= 2-[(E)-(2-chloro-phenyl-imino)-meth-yl]-6-bromo-4-chloro-phenol}, the Cu(II) atom is located on an inversion center and has a square-planar coordination. In the crystal, complex mol-ecules are linked via Cu?Cl inter-actions [2.9933?(11)?Å], forming a two-dimensional network parallel to the bc plane. They are also Cl?Cl inter-actions [3.3709?(14)?Å] present, which consolidate the two-dimensional network structure.

| S-EPMC3414162 | biostudies-other

Bis[4-bromo-2-(cyclo-pentyl-imino-meth-yl)phenolato]copper(II).

Project description:The title compound, [Cu(C(12)H(13)BrNO)(2)], was prepared by the reaction of 5-bromo-salicylaldehyde, cyclo-pentyl-amine and copper(II) acetate in an ethanol solution. The Cu(II) atom lies on an inversion center and is four-coordinated in a square-planar geometry by two N and two O atoms from two 4-bromo-2-(cyclo-pentyl-imino-meth-yl)phenolate Schiff base ligands.

| S-EPMC2968514 | biostudies-literature

Bis{4-bromo-2-[(naphthalen-1-yl-imino)-meth-yl]phenolato-?N,O}copper(II).

Project description:The title complex, [Cu(C(17)H(11)BrNO)(2)], lies on a centre of inversion. The chelating Schiff base anions define a square-planar N(2)O(2) donor set. The nearly perpendicular orientation of the naphthyl residues of the chelate ring [dihedral angle = 82.12?(12)°] precludes the Cu(II) centre from additional coordination. In the refinement, the naphthyl rings were found to be disordered over two positions.; the major component has a site occupancy of 0.667?(4).

| S-EPMC3297236 | biostudies-literature

Bis{2-[(4-bromo-phen-yl)imino-meth-yl]pyridine-κN,N'}copper(I) tetra-phenyl-borate.

Project description:In the crystal structure of the title compound, [Cu(C(12)H(9)BrN(2))(2)](C(24)H(20)B), the copper(I) cation is coordinated by four N atoms of two crystallographically independent 2-[(4-bromo-phen-yl)imino-meth-yl]pyridine ligands within a distorted tetra-hedron.

| S-EPMC2961942 | biostudies-literature

N,N'-Bis(4-chloro-phenyl-sulfon-yl)suberamide.

Project description:The asymmetric unit of the title compound, C(20)H(22)Cl(2)N(2)O(6)S(2), contains one half-mol-ecule with a center of symmetry at the mid-point of the central C-C bond. The conformations of all the N-H, C=O and C-H bonds in the central amide and aliphatic segments are anti to their adjacent bonds. The mol-ecule is bent at the S atom with a C-SO(2)-NH-C(O) torsion angle of -80.6?(4)°. The dihedral angle between the benzene ring and the SO(2)-NH-C(O)-CH(2)-CH(2)-CH(2) segment is 79.5?(2)°. In the crystal, inter-molecular N-H?O(C) and N-H?O(S) hydrogen bonds link the mol-ecules into chains along the b axis.

| S-EPMC3213543 | biostudies-literature

N,N'-Bis(2-chloro-phenyl-sulfon-yl)adipamide.

Project description:In the centrosymmetric title compound, C(18)H(18)Cl(2)N(2)O(6)S(2), the conformation of the N-H and C=O bonds in the C-SO(2)-NH-C(O)-C-C segment is anti to each other. The dihedral angle between the planes of the benzene ring and the central part of the molecule is 89.6?(2)°. In the crystal, inter-molecular N-H?O(S) hydrogen bonds link the mol-ecules into sheets along the b axis.

| S-EPMC3100076 | biostudies-literature

Bis{2-meth-oxy-6-[(3-methoxy-prop-yl)imino-meth-yl]phenolato-κN,O}copper(II).

Project description:The title complex, [Cu(C(12)H(16)NO(3))(2)], adopts a distorted square-planar coordination geometry with the Cu(II) ion situated on a crystallographic inversion center. The two Schiff base ligands are coordinated in a trans fashion. In the crystal structure, non-classical inter-molecular C-H⋯O hydrogen bonds involving the ether O atoms link the Schiff base mol-ecules into a two-dimensional network parallel to (101).

| S-EPMC2959917 | biostudies-literature

Bis[(E)-4-bromo-2-(ethoxy-imino-meth-yl)phenolato-?N,O]copper(II).

Project description:The title compound, [Cu(C(9)H(9)BrNO(2))(2)], is a centrosymmetric mononuclear copper(II) complex. The Cu atom is four-coordinated in a trans-CuN(2)O(2) square-planar geometry by two phenolate O and two oxime N atoms from two symmetry-related N,O-bidentate (E)-4-bromo-2-(ethoxy-imino-meth-yl)phenolate oxime-type ligands. An inter-esting feature of the crystal structure is the centrosymmetric inter-molecular Cu?O inter-action [3.382?(1)?Å], which establishes an infinite chain structure along the b axis.

| S-EPMC2971190 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data