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Bis[(E)-4-bromo-2-(ethoxy-imino-meth-yl)phenolato-?N,O]copper(II).

ABSTRACT: The title compound, [Cu(C(9)H(9)BrNO(2))(2)], is a centrosymmetric mononuclear copper(II) complex. The Cu atom is four-coordinated in a trans-CuN(2)O(2) square-planar geometry by two phenolate O and two oxime N atoms from two symmetry-related N,O-bidentate (E)-4-bromo-2-(ethoxy-imino-meth-yl)phenolate oxime-type ligands. An inter-esting feature of the crystal structure is the centrosymmetric inter-molecular Cu?O inter-action [3.382?(1)?Å], which establishes an infinite chain structure along the b axis.

SUBMITTER: Gong SS

PROVIDER: S-EPMC2971190 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Bis[(E)-4-bromo-2-(ethoxy-imino-meth-yl)phenolato-κN,O]copper(II).

Gong Shang-Sheng SS Dong Wen-Kui WK Tong Jun-Feng JF Li Li L Wu Jian-Chao JC

Acta crystallographica. Section E, Structure reports online 20091031 Pt 11

The title compound, [Cu(C(9)H(9)BrNO(2))(2)], is a centrosymmetric mononuclear copper(II) complex. The Cu atom is four-coordinated in a trans-CuN(2)O(2) square-planar geometry by two phenolate O and two oxime N atoms from two symmetry-related N,O-bidentate (E)-4-bromo-2-(ethoxy-imino-meth-yl)phenolate oxime-type ligands. An inter-esting feature of the crystal structure is the centrosymmetric inter-molecular Cu⋯O inter-action [3.382 (1) Å], which establishes an infinite chain structure along the ...[more]

PMID: 21578195

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