Unknown

Dataset Information

0

(E)-Methyl N'-(4-bromo-benzyl-idene)-hydrazinecarboxyl-ate at 123 K.

ABSTRACT: The title compound, C(9)H(9)BrN(2)O(2), crystallizes with two independent but essentially identical mol-ecules in the asymmetric unit. Each mol-ecule adopts a trans configuration with respect to the C=N bond. In one of the mol-ecules, the dihedral angle between the benzene ring and the hydrazinecarboxylic acid plane is 24.9?(2)°, and that in the other mol-ecule is 16.1?(2)°. The mol-ecules are linked into a three-dimensional network via inter-molecular N-H?O, C-H?O, C-H?N and C-H?Br hydrogen bonds. An intramolecular N-H?O hydrogen bond is also present.

SUBMITTER: Sun R 

PROVIDER: S-EPMC2962168 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

(E)-Methyl N'-(4-bromo-benzyl-idene)-hydrazinecarboxyl-ate at 123 K.

Sun Rong R   Cheng Xiang-Wei XW  

Acta crystallographica. Section E, Structure reports online 20080719 Pt 8

The title compound, C(9)H(9)BrN(2)O(2), crystallizes with two independent but essentially identical mol-ecules in the asymmetric unit. Each mol-ecule adopts a trans configuration with respect to the C=N bond. In one of the mol-ecules, the dihedral angle between the benzene ring and the hydrazinecarboxylic acid plane is 24.9 (2)°, and that in the other mol-ecule is 16.1 (2)°. The mol-ecules are linked into a three-dimensional network via inter-molecular N-H⋯O, C-H⋯O, C-H⋯N and C-H⋯Br hydrogen bon  ...[more]

Similar Datasets

Unknown (E)-Methyl N'-(2-hydroxy-benzyl-idene)-hydrazinecarboxyl-ate at 123 K.
| S-EPMC2962185 | biostudies-literature
Unknown (E)-Methyl 2-[4-(dimethyl-amino)benzyl-idene]hydrazinecarboxyl-ate at 123 K.
| S-EPMC2961485 | biostudies-literature
Unknown (E)-Ethyl N'-(4-bromo-benzyl-idene)hydrazinecarboxyl-ate.
| S-EPMC2962206 | biostudies-literature
Unknown Ethyl N'-[(E)-4-hydroxy-benzyl-idene]hydrazinecarboxyl-ate at 123 K.
| S-EPMC2962029 | biostudies-literature
Unknown Methyl N'-[(E)-2-methoxy-benzyl-idene]-hydrazinecarboxyl-ate.
| S-EPMC2977764 | biostudies-literature
Unknown (E)-Methyl N'-(3,4,5-trimethoxy-benzyl-idene)hydrazinecarboxyl-ate.
| S-EPMC2959621 | biostudies-literature
Unknown (E)-Methyl N'-(3,4-dimethoxy-benzyl-idene)hydrazinecarboxyl-ate.
| S-EPMC2959756 | biostudies-literature
Unknown (E)-Methyl N'-(4-hydroxy-benzyl-idene)hydrazinecarboxyl-ate.
| S-EPMC2961885 | biostudies-literature
Unknown (E)-Methyl N'-(2,4,5-trimeth-oxy-benzyl-idene)hydrazinecarboxyl-ate.
| S-EPMC3213474 | biostudies-literature
Unknown (E)-Methyl N'-(2-hydr-oxy-3-methoxy-benzyl-idene)hydrazinecarboxyl-ate.
| S-EPMC2969457 | biostudies-literature