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Potassium trifluoro-[(Z)-3-(oxan-2-yl-oxy)prop-1-en-1-yl]borate monohydrate.

ABSTRACT: The title compound, K(+)·C(8)H(13)BF(3)O(2) (-)·H(2)O, which was obtained from the reaction of a modified form of Z-vinylic telluride via a transmetalation reaction with n-BuLi, crystallizes as K(+) and C(8)H(13)BF(3)O(2) (-) ions along with a water mol-ecule. The K(+) cation is surrounded by four anions, making close contacts with six F atoms at 2.659?(3)-2.906?(3)?Å and with two O atoms at 2.806?(3) and 2.921?(3)?Å in a distorted bicapped trigonal-prismatic geometry.

SUBMITTER: Zukerman-Schpector J

PROVIDER: S-EPMC2968100 | biostudies-literature | 2008 Dec

REPOSITORIES: biostudies-literature

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Potassium trifluoro-[(Z)-3-(oxan-2-yl-oxy)prop-1-en-1-yl]borate monohydrate.

Zukerman-Schpector Julio J Guadagnin Rafael C RC Stefani Hélio A HA do Canto Visentin Lorenzo L

Acta crystallographica. Section E, Structure reports online 20081224 Pt 1

The title compound, K(+)·C(8)H(13)BF(3)O(2) (-)·H(2)O, which was obtained from the reaction of a modified form of Z-vinylic telluride via a transmetalation reaction with n-BuLi, crystallizes as K(+) and C(8)H(13)BF(3)O(2) (-) ions along with a water mol-ecule. The K(+) cation is surrounded by four anions, making close contacts with six F atoms at 2.659 (3)-2.906 (3) Å and with two O atoms at 2.806 (3) and 2.921 (3) Å in a distorted bicapped trigonal-prismatic geometry. ...[more]

PMID: 21581647

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