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La variete ?-NaMoO(2)(AsO(4)).

ABSTRACT: The title compound, sodium dioxidomolybdenum(VI) arsenate(V), ?-NaMoO(2)AsO(4), was prepared by solid-state reaction at 953?K. In the crystal structure, the AsO(4) tetra-hedra and MoO(6) octa-hedra (both with m symmetry) share corner atoms to form a three-dimensional framework that delimits cavities parallel to [010] where disordered six-coordinated sodium cations (half-occupation) are located. Structural relationships between the different orthoarsenates of the AMoO(2)AsO(4) series (A = Ag, Li, Na, K and Rb) are discussed.

SUBMITTER: Ben Hlila S 

PROVIDER: S-EPMC2968181 | biostudies-literature | 2009 Jan

REPOSITORIES: biostudies-literature

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La variété β-NaMoO(2)(AsO(4)).

Ben Hlila Soumaya S   Zid Mohamed Faouzi MF   Driss Ahmed A  

Acta crystallographica. Section E, Structure reports online 20090128 Pt 2

The title compound, sodium dioxidomolybdenum(VI) arsenate(V), β-NaMoO(2)AsO(4), was prepared by solid-state reaction at 953 K. In the crystal structure, the AsO(4) tetra-hedra and MoO(6) octa-hedra (both with m symmetry) share corner atoms to form a three-dimensional framework that delimits cavities parallel to [010] where disordered six-coordinated sodium cations (half-occupation) are located. Structural relationships between the different orthoarsenates of the AMoO(2)AsO(4) series (A = Ag, Li,  ...[more]

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