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Dichloridobis(phenyl 2-pyridyl ketone oxime)nickel(II) acetone solvate.

ABSTRACT: The Ni atom in the title compound, [NiCl(2)(C(12)H(10)N(2)O)(2)]·C(3)H(6)O, adopts a distorted octa-hedral geometry, being ligated by four N atoms from two different phenyl 2-pyridyl ketone oxime ligands and two Cl atoms. In the crystal structure, inter-molecular O-H?Cl hydrogen bonds link the mol-ecules into a chain structure along [010]. There is a ?-? contact between the pyridine rings [centroid-centroid distance = 3.824?(5)?Å].

SUBMITTER: Yin JZ 

PROVIDER: S-EPMC2968227 | biostudies-literature | 2009 Jan

REPOSITORIES: biostudies-literature

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Dichloridobis(phenyl 2-pyridyl ketone oxime)nickel(II) acetone solvate.

Yin Jing-Zhou JZ   Liu Guang-Xiang GX  

Acta crystallographica. Section E, Structure reports online 20090108 Pt 2

The Ni atom in the title compound, [NiCl(2)(C(12)H(10)N(2)O)(2)]·C(3)H(6)O, adopts a distorted octa-hedral geometry, being ligated by four N atoms from two different phenyl 2-pyridyl ketone oxime ligands and two Cl atoms. In the crystal structure, inter-molecular O-H⋯Cl hydrogen bonds link the mol-ecules into a chain structure along [010]. There is a π-π contact between the pyridine rings [centroid-centroid distance = 3.824 (5) Å]. ...[more]

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