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Fac-Aqua-dichloridotris(tetra-methyl-ene sulfoxide-?S)ruthenium(II).

ABSTRACT: The title mol-ecule, [RuCl(2)(C(4)H(8)OS)(3)(H(2)O)], is the isomer with the two chloride ligands cis and the three S-coordinated tetra-methyl-ene sulfoxide ligands facial relative to the Ru(II) center. The Ru-Cl distances are 2.4161?(7) and 2.4317?(7)?Å, the Ru-O distance is 2.1540?(19)?Å, and the Ru-S distances are in the range 2.2254?(8)-2.2657?(7)?Å, with the shortest being that trans to the aqua ligand. The coordinated water mol-ecule forms inter-molecular hydrogen bonds with Cl and sulfoxide O atoms.

SUBMITTER: Srivastava RS 

PROVIDER: S-EPMC2968404 | biostudies-literature | 2009 Jan

REPOSITORIES: biostudies-literature

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fac-Aqua-dichloridotris(tetra-methyl-ene sulfoxide-κS)ruthenium(II).

Srivastava Radhey S RS   Gonzales Carlos F CF   Fronczek Frank R FR  

Acta crystallographica. Section E, Structure reports online 20090110 Pt 2

The title mol-ecule, [RuCl(2)(C(4)H(8)OS)(3)(H(2)O)], is the isomer with the two chloride ligands cis and the three S-coordinated tetra-methyl-ene sulfoxide ligands facial relative to the Ru(II) center. The Ru-Cl distances are 2.4161 (7) and 2.4317 (7) Å, the Ru-O distance is 2.1540 (19) Å, and the Ru-S distances are in the range 2.2254 (8)-2.2657 (7) Å, with the shortest being that trans to the aqua ligand. The coordinated water mol-ecule forms inter-molecular hydrogen bonds with Cl and sulfoxi  ...[more]

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