Browse
Submit Data
Databases
API
Help

Dataset Information

8 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(2,2-Dichloro-vinyl)ferrocene.

ABSTRACT: The title compound, [Fe(C(5)H(5))(C(7)H(5)Cl(2))], represents a versatile building block for the preparation of ?-conjugated redox-active compounds or polymetallic organometallic systems due to the presence of the electrochemically active ferrocenyl unit. It is therefore a potential starting material for the preperation of the corresponding alkyne. In the crystal, the alkenyl unit and the cyclo-penta-dienide ring are almost parallel, with an angle between the best planes of only 10.6?(4)°.

SUBMITTER: Clement S

PROVIDER: S-EPMC2968422 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(2,2-Dichloro-vinyl)ferrocene.

Clément Sébastien S Clément Sébastien S Guyard Laurent L Knorr Michael M Gessner Viktoria H VH Strohmann Carsten C

Acta crystallographica. Section E, Structure reports online 20090228 Pt 3

The title compound, [Fe(C(5)H(5))(C(7)H(5)Cl(2))], represents a versatile building block for the preparation of π-conjugated redox-active compounds or polymetallic organometallic systems due to the presence of the electrochemically active ferrocenyl unit. It is therefore a potential starting material for the preperation of the corresponding alkyne. In the crystal, the alkenyl unit and the cyclo-penta-dienide ring are almost parallel, with an angle between the best planes of only 10.6 (4)°. ...[more]

PMID: 21582103

Similar Datasets

2,2-Dichloro-N-(2,5-dichloro-phen-yl)acetamide.

Project description:The conformation of the N-H bond in the title compound, C(8)H(5)Cl(4)NO, is syn to the 2-chloro substituent and anti to the 5-chloro substituent in the aromatic ring. The bond parameters are similar to those in 2,2-dichloro-N-phenyl-acetamide and other acetanilides. In the crystal structure, the mol-ecules are linked into chains through N-H?O hydrogen bonding.

| S-EPMC2915043 | biostudies-literature

2,2'-Bis(4-methoxy-phen-yl)-2,2'-bis-(tri-methyl-silan-yloxy)-2,2'-(ferrocene-1,1'-diyl)diacetonitrile.

Project description:In the title compound, [Fe(C(17)H(20)NO(2)Si)(2)], the Fe atom is situated on a crystallographic centre of inversion, leading to a perfectly staggered conformation of the Cp rings.

| S-EPMC2915074 | biostudies-literature

Bis(2,2'-bipyrid-yl)(dichloro-acetato)copper(II) dichloro-acetate dihydrate.

Project description:In the title compound, [Cu(C(2)HCl(2)O(2))(C(10)H(8)N(2))(2)](C(2)HCl(2)O(2))·2H(2)O, the Cu(II) ion is bonded to two N,N'-bidentate 2,2'-bipyridyl ligands and one O-monodentate 2,2-dichloro-acetate anion in a distorted CuON(4) trigonal-bipyramidal geometry, with the O atom occupying an equatorial site. In the crystal, the components are linked by O-H?O and O-H?Cl hydrogen bonds.

| S-EPMC2979737 | biostudies-literature

2,2-Dichloro-N-(phenyl-sulfon-yl)-acetamide.

Project description:The conformation of the N-H and C=O bonds in the title compound, C(8)H(7)Cl(2)NO(3)S, is trans. The benzene ring and the SO(2)-NH-CO-C group form a dihedral angle of 79.75?(8)°. Mol-ecules are connected via N-H?O hydrogen bonds to form linear supra-molecular chains.

| S-EPMC2962148 | biostudies-literature

4,4'-Dichloro-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenol.

Project description:The crystal of the title Schiff base compound, C(19)H(20)Cl(2)N(2)O(2), contains of two crystallographically independent mol-ecules with similar conformations. In each mol-ecule, two intramolecular O-H⋯N bonds generate S(6) motifs. The N atoms are also in close proximity to two H atoms of the dimethyl-propane groups, with H⋯N distances between 2.59 and 2.62 Å. The imine group is coplanar with the benzene ring. The dihedral angles between the benzene rings in the two independent mol-ecules are 58.20 (12) and 47.95 (12)°. The structure displays short inter-molecular Cl⋯Cl [3.3869 (11) Å] and Cl⋯O [3.175 (2)-3.204 (2) Å] inter-actions. The crystal structure is further stabilized by weak inter-molecular C-H⋯O, C-H⋯π and π-π [centroid-centroid distances 3.6416 (13)-3.8705 (14) Å] inter-actions.

| S-EPMC2967979 | biostudies-literature

4,12-Bis(2,2-dibromo-vinyl)[2.2]paracyclo-phane.

Project description:In the title compound, C(20)H(16)Br(4), both vinylic substituents were introduced by a Corey-Fuchs reaction using 4,12-diform-yl[2.2]paracyclo-phane as starting material. The title compound may be used as a valuable precursor for the synthesis of diethyn-yl[2.2]paracyclo-phane. The title mol-ecule is centrosymmetric with a crystallographic center of inversion between the centers of the two phenyl rings. A strong tilting is observed with an inter-planar angle between the best aromatic plane and the vinyl plane of 49.4?(5)°. No significant inter-molecular inter-actions are found in the crystal.

| S-EPMC2968423 | biostudies-literature

2,2-Dichloro-N-(3-nitro-phen-yl)acetamide.

Project description:The conformation of the N-H bond in the structure of the title compound (3NPDCA), C(8)H(6)Cl(2)N(2)O(3), is anti to the meta-nitro group, similar to that in the structures of 2-chloro-N-(3-nitro-phen-yl)acetamide (3NPCA) and 2,2,2-trichloro-N-(3-nitro-phen-yl)acetamide (3NPTCA), and the meta-chloro group in 2,2-dichloro-N-(3-chloro-phen-yl)acetamide (3CPDCA). The geometric parameters of 3NPDCA are similar to those of 2,2-dichloro-N-phenyl-acetamide, 3CPDCA, 3NPCA, 3NPTCA and other acetanilides. Inter-molecular N-H?O hydrogen bonds link the mol-ecules into chains running along the b axis.

| S-EPMC2960440 | biostudies-literature

2,2-Dichloro-N-(4-methyl-phenyl-sulfonyl)acetamide.

Project description:The N-H and C=O bonds in the title compound, C(9)H(9)Cl(2)NO(3)S, are trans to each other, similar to what is observed in 2,2,2-trimethyl-N-(phenyl-sulfon-yl)acetamide and 2,2,2-trimethyl-N-(4-methyl-phenyl-sulfon-yl)acetamide. The bond parameters in the title compound are also similar to those in the aforementioned two structures. N-H?O hydrogen bonds connect the mol-ecules into chains running along the a axis.

| S-EPMC2962122 | biostudies-literature

2,2-Dichloro-N-(3,5-dimethyl-phen-yl)-acetamide.

Project description:The structure of the title compound, C(10)H(11)Cl(2)NO, resembles those of 2,2-dichloro-N-phenyl-acetamide, 2,2-dichloro-N-(2-methyl-phen-yl)acetamide, 2,2-dichloro-N-(3-methyl-phen-yl)-acetamide, 2,2-dichloro-N-(4-methyl-phen-yl)acetamide, N-(3,5-dimethyl-phen-yl)acetamide and other acetanilides, with similar bond parameters. The mol-ecules in the title compound are linked into infinite chains through N-H?O and C-H?O hydrogen bonding.

| S-EPMC2915270 | biostudies-literature

2,2-Dichloro-N-(2,3-dimethyl-phen-yl)acetamide.

Project description:The conformation of the N-H bond in the title compound, C(10)H(11)Cl(2)NO, is syn to both the 2- and 3-methyl substituents in the aromatic ring, similar to that of the 2-chloro and 3-chloro substituents in 2,2-dichloro-N-(2,3-dichloro-phen-yl)acetamide and the 2-methyl substituent in 2,2-dichloro-N-(2-methyl-phen-yl)acetamide, but in contrast to the anti conformation observed with respect to the 3-methyl substituent in 2,2-dichloro-N-(3-methyl-phen-yl)acetamide. The bond parameters in the title compound are similar to those in 2,2-dichloro-N-phenyl-acetamide and other acetanilides. The mol-ecules of the title compound are linked into chains through N-H?O and C-H?O hydrogen bonding.

| S-EPMC2915294 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data