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(2,2-Dichloro-vinyl)ferrocene.

ABSTRACT: The title compound, [Fe(C(5)H(5))(C(7)H(5)Cl(2))], represents a versatile building block for the preparation of ?-conjugated redox-active compounds or polymetallic organometallic systems due to the presence of the electrochemically active ferrocenyl unit. It is therefore a potential starting material for the preperation of the corresponding alkyne. In the crystal, the alkenyl unit and the cyclo-penta-dienide ring are almost parallel, with an angle between the best planes of only 10.6?(4)°.

SUBMITTER: Clement S

PROVIDER: S-EPMC2968422 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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(2,2-Dichloro-vinyl)ferrocene.

Clément Sébastien S Clément Sébastien S Guyard Laurent L Knorr Michael M Gessner Viktoria H VH Strohmann Carsten C

Acta crystallographica. Section E, Structure reports online 20090228 Pt 3

The title compound, [Fe(C(5)H(5))(C(7)H(5)Cl(2))], represents a versatile building block for the preparation of π-conjugated redox-active compounds or polymetallic organometallic systems due to the presence of the electrochemically active ferrocenyl unit. It is therefore a potential starting material for the preperation of the corresponding alkyne. In the crystal, the alkenyl unit and the cyclo-penta-dienide ring are almost parallel, with an angle between the best planes of only 10.6 (4)°. ...[more]

PMID: 21582103

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