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2,2-Dichloro-N-(3,4-dimethyl-phen-yl)acetamide.

ABSTRACT: In the title compound, C(10)H(11)Cl(2)NO, the N-H bond is syn to the 3-methyl substituent in the aromatic ring, similar to that observed in N-(3,4-dimethyl-phen-yl)acetamide and to the 3-chloro substituent in 2,2-dichloro-N-(3,4-dichloro-phen-yl)acetamide, and contrasting with the anti conformation observed for the 3-methyl substituent in 2,2,2-trichloro-N-(3,4-dimethyl-phen-yl)acetamide. On the other hand, it is anti to the C=O bond. An inter-molecular N-H?O hydrogen bond links mol-ecules into infinite chains along the b axis.

SUBMITTER: Gowda BT

PROVIDER: S-EPMC2969347 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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2,2-Dichloro-N-(3,4-dimethyl-phen-yl)acetamide.

Gowda B Thimme BT Foro Sabine S Svoboda Ingrid I Fuess Hartmut H

Acta crystallographica. Section E, Structure reports online 20090617 Pt 7

In the title compound, C(10)H(11)Cl(2)NO, the N-H bond is syn to the 3-methyl substituent in the aromatic ring, similar to that observed in N-(3,4-dimethyl-phen-yl)acetamide and to the 3-chloro substituent in 2,2-dichloro-N-(3,4-dichloro-phen-yl)acetamide, and contrasting with the anti conformation observed for the 3-methyl substituent in 2,2,2-trichloro-N-(3,4-dimethyl-phen-yl)acetamide. On the other hand, it is anti to the C=O bond. An inter-molecular N-H⋯O hydrogen bond links mol-ecules into ...[more]

PMID: 21582880

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2,2-Dichloro-N-(2,3-dimethyl-phen-yl)acetamide.

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