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?-2,2'-(Azinodimethylene)dibenzene-sulfonato-bis-[hepta-aqua-europium(III)] bis-[2,2'-(azino-dimethylene)dibenzene-sulfonate] deca-hydrate.

ABSTRACT: In the title compound, [Eu(2)(C(14)H(10)N(2)O(6)S(2))(H(2)O)(14)](C(14)H(10)N(2)O(6)S(2))(2)·10H(2)O, the complete bimetallic cation is generated by crystallographic inversion symmetry. The Eu atom adopts a distorted dodeca-hedral coordination arising from one O-bonded 2,2'-azinodibenzene-sulfonate ligand and seven water mol-ecules. In the crystal structure, the components are linked by multiple O-H?O and O-H?N hydrogen bonds.

SUBMITTER: Tai XS

PROVIDER: S-EPMC2968462 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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μ-2,2'-(Azinodimethylene)dibenzene-sulfonato-bis-[hepta-aqua-europium(III)] bis-[2,2'-(azino-dimethylene)dibenzene-sulfonate] deca-hydrate.

Tai Xi-Shi XS

Acta crystallographica. Section E, Structure reports online 20090228 Pt 3

In the title compound, [Eu(2)(C(14)H(10)N(2)O(6)S(2))(H(2)O)(14)](C(14)H(10)N(2)O(6)S(2))(2)·10H(2)O, the complete bimetallic cation is generated by crystallographic inversion symmetry. The Eu atom adopts a distorted dodeca-hedral coordination arising from one O-bonded 2,2'-azinodibenzene-sulfonate ligand and seven water mol-ecules. In the crystal structure, the components are linked by multiple O-H⋯O and O-H⋯N hydrogen bonds. ...[more]

PMID: 21582105

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