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(4S,5R,6R)-Methyl 4-hydr-oxy-4,5-iso-propyl-idenedioxy-4,5,6,7-tetra-hydro-1,2,3-triazolo[1,5-a]pyridine-3-carboxyl-ate.

ABSTRACT: X-ray crystallography confirmed the structure of the title triazole, C(11)H(15)N(3)O(5), formed from a single-step reaction of a sugar azide with a brominated ylid. The absolute configuration was determined by the use of d-ribose as the starting material. The six-membered ring is in a half-chair conformation. The crystal structure exists as chains of O-H?O hydrogen-bonded moleclues running parallel to the b axis.

SUBMITTER: Jenkinson SF

PROVIDER: S-EPMC2968499 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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(4S,5R,6R)-Methyl 4-hydr-oxy-4,5-iso-propyl-idenedioxy-4,5,6,7-tetra-hydro-1,2,3-triazolo[1,5-a]pyridine-3-carboxyl-ate.

Jenkinson Sarah F SF Fenton Jennifer R JR Booth K Victoria KV Fleet George W J GW Watkin David J DJ

Acta crystallographica. Section E, Structure reports online 20090225 Pt 3

X-ray crystallography confirmed the structure of the title triazole, C(11)H(15)N(3)O(5), formed from a single-step reaction of a sugar azide with a brominated ylid. The absolute configuration was determined by the use of d-ribose as the starting material. The six-membered ring is in a half-chair conformation. The crystal structure exists as chains of O-H⋯O hydrogen-bonded moleclues running parallel to the b axis. ...[more]

PMID: 21582263

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