Ontology highlight
ABSTRACT:
SUBMITTER: Ng SW
PROVIDER: S-EPMC2969246 | biostudies-literature | 2009 Jun
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20090610 Pt 7
In the crystal structure of the title salt, K(3)[Pb(CH(3)COO)(2)(NCS)](NCS)(2), the [Pb(CH(3)COO)(2)(NCS)](-) anion exists as a covalently bonded entity in which the acetate anions chelate in an anisobidentate manner. The Pb atom shows a distorted ψ-octa-hedral coordination to four acetate O atoms and one isocyanate N atom, with the stereochemically active lone pair occupying one of the six sites. When the three longer Pb⋯S inter-actions are considered, the eight-coordinate geometry is based on ...[more]