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(Acetato-?O)(2-bromo-6-{[3-(dimethyl-aza-nium-yl)propyl-imino-?N]meth-yl}phenolato-?O)(thio-cyanato-?N)zinc.

ABSTRACT: In the title compound, [Zn(CH(3)COO)(NCS)(C(12)H(17)BrN(2)O)], the Zn(II) atom is four-coordinated in a distorted tetra-hedral geometry, binding to a phenolate O and an imine N atom of the Schiff base ligand, the O atom of an acetate ligand and one thio-cyanate N atom. In the crystal, mol-ecules are linked via pairs of N-H?O hydrogen bonds, forming inversion dimers.

SUBMITTER: Han CL

PROVIDER: S-EPMC3344398 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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(Acetato-κO)(2-bromo-6-{[3-(dimethyl-aza-nium-yl)propyl-imino-κN]meth-yl}phenolato-κO)(thio-cyanato-κN)zinc.

Han Cheng-Li CL

Acta crystallographica. Section E, Structure reports online 20120425 Pt 5

In the title compound, [Zn(CH(3)COO)(NCS)(C(12)H(17)BrN(2)O)], the Zn(II) atom is four-coordinated in a distorted tetra-hedral geometry, binding to a phenolate O and an imine N atom of the Schiff base ligand, the O atom of an acetate ligand and one thio-cyanate N atom. In the crystal, mol-ecules are linked via pairs of N-H⋯O hydrogen bonds, forming inversion dimers. ...[more]

PMID: 22590160

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