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Bis[1,3-bis-(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]zinc(II) dipicrate dimethyl-formamide disolvate.

ABSTRACT: In the title compound, [Zn(C(30)H(26)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Zn(II) ion is coordinated in a distorted octa-hedral environment involving four equatorial N atoms and two O atoms in axial sites. The dihedral angles between the benzimidazole ring system and the phenyl rings in each of the benzyl-benzimidazole units are 78.56?(12), 81.68?(11), 75.76?(10) and 85.78?(9)°. In the crystal structure, there are weak but significant inter-molecular ?-? stacking inter-actions with centroid-centroid distances of 3.685?(1) and 3.978?(1)?Å.

SUBMITTER: Wu H

PROVIDER: S-EPMC2969297 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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Bis[1,3-bis-(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]zinc(II) dipicrate dimethyl-formamide disolvate.

Wu Huilu H Yun Ruirui R Li Ke K Tao Sun S Wang Kaitong K

Acta crystallographica. Section E, Structure reports online 20090617 Pt 7

In the title compound, [Zn(C(30)H(26)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Zn(II) ion is coordinated in a distorted octa-hedral environment involving four equatorial N atoms and two O atoms in axial sites. The dihedral angles between the benzimidazole ring system and the phenyl rings in each of the benzyl-benzimidazole units are 78.56 (12), 81.68 (11), 75.76 (10) and 85.78 (9)°. In the crystal structure, there are weak but significant inter-molecular π-π stacking inter-actions with ce ...[more]

PMID: 21582714

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