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Bis[1,3-bis(1-propyl-1H-benzimidazol-2-yl)-2-oxapropane]-cadmium(II) dipicrate dimethyl-formamide monosolvate.

ABSTRACT: In the title compound, [Cd(C(22)H(26)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·C(3)H(7)NO, the Cd(II) ion is coordinated by four N atoms and two O atoms from two tridentate 1,3-bis-(1-propyl-1H-benzimidazol-2-yl)-2-oxopropane ligands in a distorted octa-hedral coordination environment. There are significant differences in the chemically equivalent Cd-O bond lengths [2.618?(2)?Å and 2.561?(2)?Å].

SUBMITTER: Wu H

PROVIDER: S-EPMC3201538 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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Bis[1,3-bis(1-propyl-1H-benzimidazol-2-yl)-2-oxapropane]-cadmium(II) dipicrate dimethyl-formamide monosolvate.

Wu Huilu H Kou Fan F Jia Fei F Liu Bin B Yuan Jingkun J

Acta crystallographica. Section E, Structure reports online 20110930 Pt 10

In the title compound, [Cd(C(22)H(26)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·C(3)H(7)NO, the Cd(II) ion is coordinated by four N atoms and two O atoms from two tridentate 1,3-bis-(1-propyl-1H-benzimidazol-2-yl)-2-oxopropane ligands in a distorted octa-hedral coordination environment. There are significant differences in the chemically equivalent Cd-O bond lengths [2.618 (2) Å and 2.561 (2) Å]. ...[more]

PMID: 22065501

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