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Cis-[(7R,14R)-5,5,7,12,12,14-Hexa-methyl-1,4,8,11-tetra-azacyclo-tetra-decane-?N](oxalato-?O,O')nickel(II) oxalic acid solvate.


ABSTRACT: Both mol-ecules of the title compound, [Ni(C(2)O(4))(C(16)H(36)N(4))]·C(2)H(2)O(4), are located on a crystallographic twofold rotation axis. The Ni(II) atom shows a distorted octa-hedral geometry. The crystal packing is stabilized by N-H?O and O-H?O hydrogen bonds.

SUBMITTER: Ou GC 

PROVIDER: S-EPMC2969325 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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cis-[(7R,14R)-5,5,7,12,12,14-Hexa-methyl-1,4,8,11-tetra-azacyclo-tetra-decane-κN](oxalato-κO,O')nickel(II) oxalic acid solvate.

Ou Guang-Chuan GC   Dai Yong-Qiang YQ   Tang Man-Sheng MS  

Acta crystallographica. Section E, Structure reports online 20090606 Pt 7


Both mol-ecules of the title compound, [Ni(C(2)O(4))(C(16)H(36)N(4))]·C(2)H(2)O(4), are located on a crystallographic twofold rotation axis. The Ni(II) atom shows a distorted octa-hedral geometry. The crystal packing is stabilized by N-H⋯O and O-H⋯O hydrogen bonds. ...[more]

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