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{Bis[4-(2-pyrid-yl)pyrimidin-2-yl]sulfane}dichloridocobalt(II).


ABSTRACT: The asymmetric unit of the title compound, [CoCl(2)(C(18)H(12)N(6)S)], contains one half-mol-ecule situated on a twofold rotation axis which passes through the Co and S atoms. The metal centre is in a distorted octahedral CoCl(2)N(4) coordination with the Cl atoms in the axial positions. In the crystal structure, inter-molecular C-H?Cl inter-actions help to establish the packing.

SUBMITTER: Zhu HB 

PROVIDER: S-EPMC2969327 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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{Bis[4-(2-pyrid-yl)pyrimidin-2-yl]sulfane}dichloridocobalt(II).

Zhu Hai-Bin HB   Li Lei L   Ji Jun-Feng JF  

Acta crystallographica. Section E, Structure reports online 20090617 Pt 7


The asymmetric unit of the title compound, [CoCl(2)(C(18)H(12)N(6)S)], contains one half-mol-ecule situated on a twofold rotation axis which passes through the Co and S atoms. The metal centre is in a distorted octahedral CoCl(2)N(4) coordination with the Cl atoms in the axial positions. In the crystal structure, inter-molecular C-H⋯Cl inter-actions help to establish the packing. ...[more]

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