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{2,6-Bis[1-(phenyl-imino)eth-yl]pyridine-?N,N',N''}dichloridocobalt(II).

ABSTRACT: In the title complex, [CoCl(2)(C(21)H(19)N(3))], the Co(II) atom is coordinated by one pyridine and two imine N atoms and by two chloride anions in a distorted trigonal bipyramidal geometry. The structure exhibits a pseudo-mirror plane through the metal atom, two chloride anions and the pyridine ring. In the crystal structure, the complexes are connected via inter-molecular C-H?Cl hydrogen bonding.

SUBMITTER: Li XG

PROVIDER: S-EPMC2961630 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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{2,6-Bis[1-(phenyl-imino)eth-yl]pyridine-κN,N',N''}dichloridocobalt(II).

Li Xiao-Gang XG Zhong Di-Chang DC He Ren R Guo Hui-Rui HR

Acta crystallographica. Section E, Structure reports online 20080507 Pt 6

In the title complex, [CoCl(2)(C(21)H(19)N(3))], the Co(II) atom is coordinated by one pyridine and two imine N atoms and by two chloride anions in a distorted trigonal bipyramidal geometry. The structure exhibits a pseudo-mirror plane through the metal atom, two chloride anions and the pyridine ring. In the crystal structure, the complexes are connected via inter-molecular C-H⋯Cl hydrogen bonding. ...[more]

PMID: 21202475

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