Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(?-Acetato){?-1,3-bis[2-(2-oxidobenzylideneamino)ethyl]-2-(2-oxidophenyl)-1,3-imidazolidine}dizinc(II) ethanol disolvate dihydrate.

ABSTRACT: In the title binuclear compound, [Zn(2)(C(27)H(27)N(4)O(3))(C(2)H(3)O(2))]·2CH(3)CH(2)OH·2H(2)O, both Zn cations adopt distorted ZnO(3)N(2) trigonal-bipyramidal geometries with one N atom in a axial site and one N atom in an equatorial site, arising from coordination by the N,N,N,N,O,O,O-hepta-dentate ligand and a bridging acetate ion. In the crystal, inter-molecular O-H?O hydrogen bonds link the component units into a three-dimensional network. Two short C-H?O contacts are also seen.

SUBMITTER: Lu XP

PROVIDER: S-EPMC2969424 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(μ-Acetato){μ-1,3-bis[2-(2-oxidobenzylideneamino)ethyl]-2-(2-oxidophenyl)-1,3-imidazolidine}dizinc(II) ethanol disolvate dihydrate.

Lu Xiao-Ping XP Zhu Miao-Li ML Lu Li-Ping LP

Acta crystallographica. Section E, Structure reports online 20090606 Pt 7

In the title binuclear compound, [Zn(2)(C(27)H(27)N(4)O(3))(C(2)H(3)O(2))]·2CH(3)CH(2)OH·2H(2)O, both Zn cations adopt distorted ZnO(3)N(2) trigonal-bipyramidal geometries with one N atom in a axial site and one N atom in an equatorial site, arising from coordination by the N,N,N,N,O,O,O-hepta-dentate ligand and a bridging acetate ion. In the crystal, inter-molecular O-H⋯O hydrogen bonds link the component units into a three-dimensional network. Two short C-H⋯O contacts are also seen. ...[more]

PMID: 21582672

Similar Datasets

Crystal structure of bis-(acetato-κO)bis-(pyridine-2-carboxamide oxime-κ(2) N,N')cadmium ethanol disolvate.

Project description:In the title compound, [Cd(CH3COO)2(C6H7N3O)2]·2C2H5OH, the Cd(II) atom, which lies on a twofold rotation axis, is coordinated by two monodentate acetate groups and two N,N'-chelating pyridine-2-carboxamide oxime ligands, leading to a distorted octahedral coordination sphere. The mononuclear complex mol-ecules are assembled into chains along the c-axis direction via N-H⋯O hydrogen-bonding inter-actions. These chains are further assembled by O-H⋯O hydrogen bonds involving the ethanol solvent mol-ecules into a three-dimensional supramolecular structure.

| S-EPMC4186130 | biostudies-literature

Tetra-?(2)-acetato-diaqua-bis-(?(2)-2-{[1,3-dihy-droxy-2-(oxidometh-yl)propan-2-yl]imino-meth-yl}phenolato)trimanganese(II,III) acetonitrile disolvate dihydrate.

Project description:In the title complex, [Mn(II)Mn(III) (2)(C(11)H(13)NO(4))(2)(CH(3)CO(2))(4)(H(2)O)(2)]·2CH(3)CN·2H(2)O, there are two Mn(III) and one Mn(II) atoms. The Mn(II) atom lies on an inversion center and the Mn(III)-Mn(II)-Mn(III) angle is therefore 180°, as required by crystallographic symmetry. The Mn(III) and Mn(II) atoms are six-coordinated in a distorted octa-hedral geometry. In the crystal, complex mol-ecules and solvent mol-ecules are linked into a three-dimensional network by O-H?O and O-H?N hydrogen-bonding inter-actions.

| S-EPMC3212170 | biostudies-literature

Aqua-[1,3-bis-(benzimidazol-2-yl)-2-oxapropane]-diethano-lmanganese(II) dipicrate ethanol disolvate.

Project description:In the title complex, [Mn(C(16)H(14)N(4)O)(C(2)H(5)OH)(2)(H(2)O)](C(6)H(2)N(3)O(7))(2)·2C(2)H(5)OH, the Mn(II) ion is in a distorted octa-hedral coordination environment, defined by an MnN(2)O(4) donor set. The 1,3-bis-(benz-imid-azol-2-yl)-2-oxapropane ligand is tridentate. In the crystal structure, inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the components into a three-dimensional network. The O atoms of one of the nitro groups are disordered over two sets of sites with refined occupancies of 0.577 (11) and 0.423 (11).

| S-EPMC3008082 | biostudies-literature

Tetra-aqua-bis[(1-carboxyl-atomethyl-1,3-benzimidazol-3-ium-3-yl)acetato-κO]palladium(II) dihydrate.

Project description:In the title compound, [Pd(C(11)H(9)N(2)O(4))(2)(H(2)O)(4)]·2H(2)O, the palladium(II) cation lies on an inversion centre and is hexa-coordinated by two carboxyl-ate O atoms from two (1-carboxyl-atomethyl-1,3-benzimidazol-3-ium-3-yl)acetate ligands and four water mol-ecules, with a slightly distorted octa-hedral geometry. O-H⋯O hydrogen bonds link the mol-ecules together.

| S-EPMC2961856 | biostudies-literature

1,3-Bis(1-phenyl-eth-yl)imidazolidine-2-thione.

Project description:The complete molecule of the title compound, C(19)H(22)N(2)S, is generated by crystallographic twofold symmetry with the C=S group lying on the rotation axis. The imidazolidine ring adopts a flattened twist conformation. The dihedral angle between the asymmetric part of the imidazolidine-2-thione fragment and the benzene ring is 89.49?(17)°.

| S-EPMC3344125 | biostudies-literature

1,1'-[Imidazolidine-1,3-diylbis(methyl-ene)]bis-(1H-benzotriazole).

Project description:In the title compound, C(17)H(18)N(8), the imidazolidine ring adopts an envelope conformation with the substituents at the N atoms in trans positions with respect to the central ring. The dihedral angle between the two benzotriazole rings is 71.65?(10)°. In the crystal, non-classical C-H?N inter-actions link the mol-ecules into helical chains along the b axis. The crystal packing is further stabilized by weak C-H?? inter-actions.

| S-EPMC3275003 | biostudies-literature

1,3-Bis(4-chloro-phen-yl)-4,5-diethoxy-imidazolidine.

Project description:In the mol-ecule of the title compound, C(19)H(22)Cl(2)N(2)O(2), the two benzene rings are oriented at a dihedral angle of 3.70 (3)°. The five-membered ring adopts an envelope conformation.

| S-EPMC2959530 | biostudies-literature

Bis{?-1,3-bis-[2-(5-bromo-2-oxidobenzyl-idene-amino)ethyl]-2-(5-bromo-2-oxido-phenyl)-1,3-imidazolidine}dineo-dymium(III) N,N-dimethyl-formamide hexa-solvate.

Project description:In the title centrosymmetric dinuclear complex, [Nd(2)(C(27)H(24)Br(3)N(4)O(3))(2)]·6C(3)H(7)NO, the Nd(III) ion is coordinated in a slightly distorted square-anti-prismatic geometry by four N atoms and four O atoms from two centrosymmetrically-related 1,3-bis-[2-(5-bromo-2-oxidobenzyl-amino)eth-yl]-2-(5-bromo-2-oxidophen-yl)-1,3-imidazolidine ligands. The Nd?Nd separation is 4.5012?(12)?Å.

| S-EPMC2972062 | biostudies-literature

Crystal structure of di-aqua-(μ2-tri-ethyl-ene-tetra-minehexa-acetato)-dizinc tetra-hydrate.

Project description:The reaction of ZnO and tri-ethyl-ene-tetra-minehexaacetic acid (H6TTHA) in aqueous solution after refluxing yields the binuclear title compound, [Zn2(C18H26N4O12)(H2O)2]·4H2O. There is a centre of symmetry in the [Zn2(H2TTHA)(H2O)2] mol-ecule in the crystalline state. Both Zn(II) ions are octahedrally surrounded and bound by an N2O3 donor set from the H2TTHA(4-) anion and a water mol-ecule; the N atoms are cis and the water mol-ecule is trans to an N atom. The Zn⋯Zn separation is 7.562 (1) Å. An intra-molecular C-H⋯O inter-action is observed and both carboxyl-ate H atoms are disordered over two adjacent sites. In the crystal, the components are linked by O-H⋯O and C-H⋯O hydrogen bonds generating a three-dimensonal network.

| S-EPMC4350722 | biostudies-literature

Bis(?-2-phenyl-acetato-?O:O)bis-[(2,2'-bipyridyl-?N,N')(2-phenyl-acetato-?O)copper(II)] dihydrate.

Project description:The mol-ecule of the binuclear title complex, [Cu(2)(C(8)H(7)O(2))(4)(C(10)H(8)N(2))(2)]·2H(2)O, is located on an inversion centre. The Cu atoms are bridged by two O atoms of the monodentate phenyl-acetate groups [Cu-O = 1.9808?(14) and 2.3668?(14)?Å]. The longer of the two bridging Cu-O bonds takes the apical position of the distorted square-pyramidal environment of the Cu atom, which is completed by two N atoms of the chelate 2,2'-bipyridine ligand [Cu-N = 2.0107?(17) and 2.0234?(16)?Å]. The mol-ecules are assembled into stacks along [100] through ?-? inter-actions with inter-planar distances of 3.630?(4) and 3.407?(3)?Å; the resulting stacks are further connected into a three-dimensional supra-molecular architecture by O-H?O and C-H?O hydrogen-bonding inter-actions.

| S-EPMC3201355 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data