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Bis(2-chloro-benz-yl)dimethyl-ammonium bromide.

ABSTRACT: In the title compound, C(16)H(18)Cl(2)N(+)·Br(-), the dihedral angle between the aromatic ring planes is 57.73?(5)°. In the absence of any strong hydrogen bonds, the structure results from a large number of competing weaker inter-actions including Cl?Cl [3.4610?(5)?Å] and C-H?Cl contacts and both (aryl) C-H?Br and N(+)-Csp(3)-H?Br(-) cation-anion inter-actions.

SUBMITTER: Mahmud T

PROVIDER: S-EPMC2969506 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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Bis(2-chloro-benz-yl)dimethyl-ammonium bromide.

Mahmud Tariq T Iqbal Javed J Elsegood Mark R J MR McKee Vickie V McKee Vickie V

Acta crystallographica. Section E, Structure reports online 20090613 Pt 7

In the title compound, C(16)H(18)Cl(2)N(+)·Br(-), the dihedral angle between the aromatic ring planes is 57.73 (5)°. In the absence of any strong hydrogen bonds, the structure results from a large number of competing weaker inter-actions including Cl⋯Cl [3.4610 (5) Å] and C-H⋯Cl contacts and both (aryl) C-H⋯Br and N(+)-Csp(3)-H⋯Br(-) cation-anion inter-actions. ...[more]

PMID: 21582850

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