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2-Phenyl-1-(phenyl-sulfin-yl)naphtho[2,1-b]furan.

ABSTRACT: In the title compound, C(24)H(16)O(2)S, the O atom and the phenyl group of the phenyl-sulfinyl substituent lie on opposite sides of the plane of the naphthofuran fragment; the phenyl ring is almost perpendicular to this plane [82.34?(5)°]. The 2-phenyl ring is rotated out of the naphthofuran plane making a dihedral angle of 48.21?(6)°. The crystal structure shows ?-? inter-actions between the central benzene rings of adjacent mol-ecules [centroid-centroid distance = 3.516?(3)?Å], as well as non-classical C-H?O hydrogen bonds.

SUBMITTER: Choi HD

PROVIDER: S-EPMC2969545 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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2-Phenyl-1-(phenyl-sulfin-yl)naphtho[2,1-b]furan.

Choi Hong Dae HD Seo Pil Ja PJ Son Byeng Wha BW Lee Uk U

Acta crystallographica. Section E, Structure reports online 20090529 Pt 6

In the title compound, C(24)H(16)O(2)S, the O atom and the phenyl group of the phenyl-sulfinyl substituent lie on opposite sides of the plane of the naphthofuran fragment; the phenyl ring is almost perpendicular to this plane [82.34 (5)°]. The 2-phenyl ring is rotated out of the naphthofuran plane making a dihedral angle of 48.21 (6)°. The crystal structure shows π-π inter-actions between the central benzene rings of adjacent mol-ecules [centroid-centroid distance = 3.516 (3) Å], as well as non- ...[more]

PMID: 21583281

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