Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Dibromido[(tert-butyl-amino)dimeth-yl(piperidin-1-ylmeth-yl)silane-?N,N']zinc(II).

ABSTRACT: The title compound, [ZnBr(2)(C(12)H(28)N(2)Si)], is an example of a neutral coordination compound of a bidentate ligand to a metal centre with the Zn atom being coordinated by two Br and two N atoms, yielding a slightly distorted tetra-hedral coordination environment.

SUBMITTER: Colquhoun VP

PROVIDER: S-EPMC2969557 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Dibromido[(tert-butyl-amino)dimeth-yl(piperidin-1-ylmeth-yl)silane-κN,N']zinc(II).

Colquhoun Victoria P VP Strohmann Carsten C

Acta crystallographica. Section E, Structure reports online 20090523 Pt 6

The title compound, [ZnBr(2)(C(12)H(28)N(2)Si)], is an example of a neutral coordination compound of a bidentate ligand to a metal centre with the Zn atom being coordinated by two Br and two N atoms, yielding a slightly distorted tetra-hedral coordination environment. ...[more]

PMID: 21583039

Similar Datasets

Tetra-kis(4-tert-butyl-benz-yl)silane.

Project description:The title compound, C(44)H(60)Si, was prepared as an inter-nal standard for diffusion-ordered NMR spectroscopy. The Si atom lies on a special position with site symmetry.

| S-EPMC3007930 | biostudies-literature

2-tert-Butyl-4-methyl-6-(1,3-oxazinan-1-ylmeth-yl)phenol.

Project description:The title compound, C(16)H(25)NO(2), which was synthesized by a Mannich reaction route, is a rare example of an organic compound containing the six-membered oxazine ring. The ring adopts a chair conformation and the N atom is pyramidal. The N atom serves as a hydrogen-bond acceptor to the phenolic OH group.

| S-EPMC2979180 | biostudies-literature

tert-Butyl N-(5-bromo-1H-imidazo[4,5-b]pyridin-2-ylmeth-yl)carbamate.

Project description:In the mol-ecule of the title compound, C(12)H(15)BrN(4)O(2), the imidazole and pyridine rings are strictly coplanar [maximum deviation 0.006 (3) Å]. In the crystal structure, mol-ecules are linked into chains running parallel to the a axis by inter-molecular N-H⋯O hydrogen bonds. Centrosymmetrically related chains are further connected by N-H⋯N hydrogen-bonding inter-actions to form a two-dimensional layer structure parallel to the ab plane.

| S-EPMC2959901 | biostudies-literature

2,6-Di-tert-butyl-4-(dimethyl-amino-meth-yl)phenol.

Project description:The title compound, C(17)H(29)NO, is an important hindered phenol derivative. The asymmetric unit contains two mol-ecules. Molecules inter-act through O-H?N hydrogen bonds to form a tetramer arranged around a twofold rotation axis.

| S-EPMC2915276 | biostudies-literature

Bis[?-N-(tert-butyl-dimethyl-silyl)-N-(pyridin-2-ylmeth-yl)amido]-bis-[methyl-cobalt(II)].

Project description:The green title complex, [Co(2)(CH(3))(2)(C(12)H(21)N(2)Si)(2)], was obtained from bis-{[?-N-tert-butyl-dimethyl-silyl-N-(pyridin-2-ylmeth-yl)amido]-chloridocobalt(II)} and methyl-lithium in diethyl ether at 195?K via a metathesis reaction. The dimeric cobalt(II) complex exhibits a crystallographic center of inversion in the middle of the Co(2)N(2) ring (average Co-N = 2.050?Å). The Co(II) atom shows a distorted tetra-hedral coordination sphere. The exocyclic Co-N bond length to the pyridyl group shows a similar value of 2.045?(4)?Å. The exocyclic methyl group has a rather long Co-C bond length of 2.019?(5)?Å.

| S-EPMC3435591 | biostudies-literature

Dibromido[bis-(η-cyclo-penta-dien-yl)dimethyl-silane]zirconium(IV).

Project description:The title mol-ecule, [ZrBr(2)(C(12)H(14)Si)], possesses a crystallographically imposed twofold rotational symmetry with the rotation axis passing through the Zr and Si atoms. The Zr(IV) centre is in a distorted tetra-hedral environment defined by two Cp rings of chelating organic ligands and two Br anions. Two five-membered rings form a dihedral angle of 59.7 (2)°. Unequal Zr-C bonds [2.471 (3)-2.556 (3) Å] in the mol-ecule indicate that the inter-action of the central metal with the [(C(5)H(4))(2)SiMe(2)](2-) ligand contains noticeable η(3)-allyl and η(2)-olefin contributions.

| S-EPMC2967924 | biostudies-literature

1-(4-tert-Butyl-benz-yl)-2-(4-tert-butyl-phen-yl)-1H-benzimidazole.

Project description:In the mol-ecule of the title compound, C(28)H(32)N(2), the benzimidazole ring system is almost planar [maximum deviation = 0.0221 (15) Å] and forms dihedral angles of 85.86 (4) and 32.09 (6)° with the benzene rings. In the crystal structure, mol-ecules are linked into chains running parallel to the a axis by inter-molecular C-H⋯N hydrogen bonds. The methyl groups of a tert-butyl group are rotationally disordered over two positions with refined site-occupancy factors of 0.636 (4) and 0.364 (4).

| S-EPMC2971974 | biostudies-literature

(E)-2-[(2-Amino-phen-yl)imino-meth-yl]-4,6-di-tert-butyl-phenol.

Project description:In the title compound, C(21)H(28)N(2)O, the dihedral angle between the rings is 35.2?(2)°. A weak intra-molecular O-H?N hydrogen bond is observed between the O-H H atom and the imine N atom. In the crystal, mol-ecules are linked by additional inter-molecular N-H?O hydrogen bonding, resulting in a wave-like chain along the b-axis direction.

| S-EPMC3470314 | biostudies-literature

tert-Butyl N-{2-[bis-(prop-2-yn-1-yl)amino]-phen-yl}carbamate.

Project description:In the crystal of the title compound, C(17)H(20)N(2)O(2), the molecules are linked by C-H?O interactions. Intra-molecular C-H?O and N-H?N hydrogen bonds also occur.

| S-EPMC3120597 | biostudies-literature

1,1,3,3-Tetra-tert-butyl-2,2-diisopropyl-4,4-diphenyl-cyclo-tetra-silane.

Project description:The molecule in the structure of the title compound, C34H60Si4, lies on a twofold rotation axis that passes through the two Si atoms, resulting in a planar cyclo-tetra-silane ring. The dihedral angle between the cyclo-tetra-silane ring and the phenyl ring is 68.20?(5)°. The Si-Si bonds [2.4404?(8) and 2.4576?(8)?Å] are longer than a standard Si-Si bond (2.34?Å) and the C-Si-C bond angle [97.07?(14)°] of the phenyl-substituted Si atom is smaller than the tetra-hedral bond angle (109.5°). These long bonds and small bond angle are favorable for reducing the steric hindrance among the bulky substituents.

| S-EPMC3588281 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data