Browse
Submit Data
Databases
API
Help

Dataset Information

12 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

1-[(3-Methyl-piperidin-1-yl)(phen-yl)meth-yl]-2-naphthol.

ABSTRACT: In the title compound, C(23)H(25)NO, the dihedral angle between the naphthyl-ene ring system and the benzene ring is 78.17?(10)°. The mol-ecular conformation is stabilized by a strong intra-molecular O-H?N hydrogen bond.

SUBMITTER: Wang WX

PROVIDER: S-EPMC2969577 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

1-[(3-Methyl-piperidin-1-yl)(phen-yl)meth-yl]-2-naphthol.

Wang Wen Xiang WX Zhao Hong H

Acta crystallographica. Section E, Structure reports online 20090514 Pt 6

In the title compound, C(23)H(25)NO, the dihedral angle between the naphthyl-ene ring system and the benzene ring is 78.17 (10)°. The mol-ecular conformation is stabilized by a strong intra-molecular O-H⋯N hydrogen bond. ...[more]

PMID: 21583139

Similar Datasets

1-[(2-Methyl-piperidin-1-yl)(phen-yl)meth-yl]naphthalen-2-ol.

Project description:In the title compound, C(23)H(25)NO, an intra-molecular O-H?N hydrogen bond defines the mol-ecular conformation; the naphthol mean plane and the benzene ring form a dihedral angle of 75.8?(2)°. The piperidine ring adopts a chair conformation. The crystal packing exhibits no short inter-molecular contacts.

| S-EPMC3470315 | biostudies-literature

1-[Morpholino(phen-yl)meth-yl]-2-naphthol.

Project description:There are two independent mol-ecules in the asymmetric unit of the title compound, C(21)H(21)NO(2), which was synthesized by the one-pot reaction of 2-naphthol, morpholine and benzaldehyde. The dihedral angles between the naphthalene ring systems and the benzene rings are 84.03?(7) and 75.76?(8)° in the two mol-ecules and an intra-molecular O-H?N hydrogen bond occurs in each independent mol-ecule.

| S-EPMC2979465 | biostudies-literature

1-[(3-Methyl-piperidin-1-yl)(3-nitro-phen-yl)meth-yl]naphthalen-2-ol.

Project description:The title compound, C(23)H(24)N(2)O(3), was synthesized from naphthalen-2-ol, 3-nitro-benzaldehyde and 3-methyl-piperidine. The dihedral angles between the naphthalene system and the nitro-benzene and methyl-piperidine rings are 78.53?(13) and 64.14?(15)°, respectively. The mol-ecular conformation is stabilized by a strong intra-molecular O-H?N hydrogen bond.

| S-EPMC3011680 | biostudies-literature

1-[Phen-yl(pyridin-2-yl-amino)-meth-yl]-2-naphthol.

Project description:The title compound, C(22)H(18)N(2)O, was synthesized from naphthalen-2-ol, benzaldehyde and pyridin-2-amine. In the crystal, mol-ecules are linked into centrosymmetric R(2) (2)(16) dimers by pairs of O-H?N hydrogen bonds. The mol-ecular conformation is stabilized by an N-H?O hydrogen bond. The dihedral angle between the naphthylene ring system and the phenyl ring is 72.86?(12)°.

| S-EPMC3009335 | biostudies-literature

1-[(E)-(2-Methyl-3-nitro-phen-yl)imino-meth-yl]-2-naphthol.

Project description:The title Schiff base compound, C(18)H(14)N(2)O(3), has an inter-mediate state between NH and OH tautomers. The mol-ecular structure is stabilized by an O-H?N hydrogen bond. The dihedral angle between the naphthalene ring system and the benzene ring is 37.44?(5)°.

| S-EPMC3011447 | biostudies-other

1-{Phen-yl[1-(p-tol-yl)ethyl-amino]meth-yl}-2-naphthol.

Project description:The title compound, C(26)H(25)NO, was obtained via a one-pot synthesis from the reaction of 2-naphthol, 1-(p-tol-yl)ethyl-amine, p-toluene-sulfonic acid and benzaldehyde. There are three mol-ecules per asymmetric unit, all having similar conformations. There are intra-molecular O-H?N and C-H?O hydrogen bonds, with only van der Waals forces found between mol-ecules.

| S-EPMC2959420 | biostudies-literature

1-Methyl-2-({[(2-methyl-phen-yl)meth-yl]disulfan-yl}meth-yl)benzene.

Project description:In the title disulfide, C(16)H(18)S(2), the mol-ecule is twisted about the central S-S bond [the C-S-S-C torsion angle = 93.24?(7)°] and the dihedral angle between the benzene rings is 72.84?(7)°, indicating an almost orthogonal relationship; the methyl groups are orientated to the same side of the mol-ecule. The crystal packing features C-H?.? inter-actions which consolidate a three-dimensional architecture.

| S-EPMC3379504 | biostudies-literature

1-[(3-Nitro-phen-yl)(piperidin-1-yl)methyl]piperidine.

Project description:In the crystal structure of the title compound, C(17)H(25)N(3)O(2), one-dimensional chains are formed via inter-molecular C-H?O hydrogen bonds along the a axis.

| S-EPMC3379494 | biostudies-literature

Crystal structure of benz-yl(meth-yl)phen-yl[(piperidin-1-ium-1-yl)meth-yl]silane bromide.

Project description:The title compound, C20H29NSi(+)·Br(-), contains a chiral silicon atom but crystallizes as a racemate. The C-Si-C bond angles in the range of 103.64?(8)-111.59?(9)° are usual for tetra-hedral geometry. The piperidine ring shows a regular chair conformation with an equatorially positioned exocyclic N-C bond. In the crystal, there is a hydrogen bond between the ammonium cation and the bromide anion. The crystal packing shows the dominant inter-molecular inter-action to be the electrostatic attraction between the ammonium cation and the bromide anion.

| S-EPMC4647413 | biostudies-literature

(E)-1-[(2-Fluoro-phen-yl)imino-meth-yl]-2-naphthol-(Z)-1-[(2-fluoro-phen-yl)amino-methyl-idene]naphthalen-2(1H)-one (0.57/0.43).

Project description:The title Schiff base compound, 0.57C(17)H(12)FNO·0.43C(17)H(12)FNO, reveals both the enol (OH) and keto (NH) tautomeric forms with occupancies of 0.57?(6) and 0.43?(6), respectively. The tautomeric forms are stabilized by intra-molecular O-H?N (enol) and N-H?O (keto) hydrogen bonds. The dihedral angle between the naphthalene ring system and the benzene ring is 32.76?(1)°.

| S-EPMC2979202 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data