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Aqua-bis(4-nitro-benzoato)-?O,O';?O-(piperidinium-4-carboxyl-ato-?O,O')cadmium(II).

ABSTRACT: In the mixed ligand title compound, [Cd(C(6)H(11)NO(2))(C(7)H(4)NO(4))(2)(H(2)O)], which exhibits a discrete mononuclear structure, the Cd(II )atom is in a distorted octa-hedral geometry, surrounded by five carboxyl-ate O atoms and one coordinated water mol-ecule. The piperdinium ring adopts a chair conformation and the two 4-nitro-benzoate rings are oriented at a dihedral angle of 75.8?(1)°. Inter-molecular O-H?O and N-H?O hydrogen bonds link the mononuclear entities into a three-dimensional supra-molecular network.

SUBMITTER: Zhang RW

PROVIDER: S-EPMC2969669 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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Aqua-bis(4-nitro-benzoato)-κO,O';κO-(piperidinium-4-carboxyl-ato-κO,O')cadmium(II).

Zhang Run-Wen RW Wang Li-Li LL Zhao Xiao-Jun XJ

Acta crystallographica. Section E, Structure reports online 20090520 Pt 6

In the mixed ligand title compound, [Cd(C(6)H(11)NO(2))(C(7)H(4)NO(4))(2)(H(2)O)], which exhibits a discrete mononuclear structure, the Cd(II )atom is in a distorted octa-hedral geometry, surrounded by five carboxyl-ate O atoms and one coordinated water mol-ecule. The piperdinium ring adopts a chair conformation and the two 4-nitro-benzoate rings are oriented at a dihedral angle of 75.8 (1)°. Inter-molecular O-H⋯O and N-H⋯O hydrogen bonds link the mononuclear entities into a three-dimensional su ...[more]

PMID: 21583026

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