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Diazido-bis[2,4-diamino-6-(2-pyrid-yl)-1,3,5-triazine-?N,N]zinc(II).

ABSTRACT: In the title mononuclear complex, [Zn(N(3))(2)(C(8)H(8)N(6))(2)], the Zn(II) atom, lying on a twofold rotation axis, is six-coordinated in a distorted octa-hedral environment by four N atoms from two 2,4-diamino-6-(2-pyrid-yl)-1,3,5-triazine ligands and two N atoms from two end-on-coordinated azide ions. N-H?N hydrogen bonds between the ligand and azide ion link the complex mol-ecules into a three-dimensional network.

SUBMITTER: Zhao QH

PROVIDER: S-EPMC2969763 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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Diazido-bis[2,4-diamino-6-(2-pyrid-yl)-1,3,5-triazine-κN,N]zinc(II).

Zhao Qi-Hua QH Fan Ai-Ling AL Li Li-Nan LN Xie Ming-Jing MJ

Acta crystallographica. Section E, Structure reports online 20090507 Pt 6

In the title mononuclear complex, [Zn(N(3))(2)(C(8)H(8)N(6))(2)], the Zn(II) atom, lying on a twofold rotation axis, is six-coordinated in a distorted octa-hedral environment by four N atoms from two 2,4-diamino-6-(2-pyrid-yl)-1,3,5-triazine ligands and two N atoms from two end-on-coordinated azide ions. N-H⋯N hydrogen bonds between the ligand and azide ion link the complex mol-ecules into a three-dimensional network. ...[more]

PMID: 21582992

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