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4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate.


ABSTRACT: In the cation of the title compound, C(22)H(19)N(2) (+)·NO(3) (-), the N atom in the 3-position of the imidazole is protonated. The three pendant aromatic rings are twisted from the plane of the imadazolium ring by dihedral angles of 38.1 (1), 43.74 (9) and 20.4 (1)°. In the crystal structure, N-H⋯O and N-H⋯(O,O) hydrogen bonds link the mol-ecules to form an infinite one-dimensional chain parallel to the c axis.

SUBMITTER: Cui LJ 

PROVIDER: S-EPMC2969798 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate.

Cui Li-Jing LJ  

Acta crystallographica. Section E, Structure reports online 20090523 Pt 6


In the cation of the title compound, C(22)H(19)N(2) (+)·NO(3) (-), the N atom in the 3-position of the imidazole is protonated. The three pendant aromatic rings are twisted from the plane of the imadazolium ring by dihedral angles of 38.1 (1), 43.74 (9) and 20.4 (1)°. In the crystal structure, N-H⋯O and N-H⋯(O,O) hydrogen bonds link the mol-ecules to form an infinite one-dimensional chain parallel to the c axis. ...[more]

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