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1-Chloro-acetyl-2,6-bis-(2-methoxy-phen-yl)-3,5-dimethyl-piperidin-4-one.

ABSTRACT: The piperidone ring in the title compound, C(23)H(26)ClNO(4), adopts a boat conformation with its two out-of-plane C atoms deviating by 0.597?(2) and 0.630?(2)?Å from the least-squares plane of the rest of atoms in the ring. The two aromatic rings are roughly perpendicular to each other, making a dihedral angle of 75.1?(1)°, and a C-H?? intra-molecular inter-action is observed. The crystal packing is stabilized by a C-H?O inter-molecular inter-action, generating a chain with a C(9) motif along the a axis.

SUBMITTER: Aridoss G 

PROVIDER: S-EPMC2970045 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

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1-Chloro-acetyl-2,6-bis-(2-methoxy-phen-yl)-3,5-dimethyl-piperidin-4-one.

Aridoss G G   Gayathri D D   Velmurugan D D   Kim M S MS   Jeong Yeon Tae YT  

Acta crystallographica. Section E, Structure reports online 20090829 Pt 9

The piperidone ring in the title compound, C(23)H(26)ClNO(4), adopts a boat conformation with its two out-of-plane C atoms deviating by 0.597 (2) and 0.630 (2) Å from the least-squares plane of the rest of atoms in the ring. The two aromatic rings are roughly perpendicular to each other, making a dihedral angle of 75.1 (1)°, and a C-H⋯π intra-molecular inter-action is observed. The crystal packing is stabilized by a C-H⋯O inter-molecular inter-action, generating a chain with a C(9) motif along t  ...[more]

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