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N-Cyano-7?-methoxy-carbonyl-6,14-endo-ethenotetra-hydro-northebaine.

ABSTRACT: IN THE TITLE COMPOUND (SYSTEMATIC NAME:methyl 17-cyano-3,6-dimeth-oxy-4,5?-ep-oxy-6,14-endo-ethenomorphinan-7-carboxyl-ate), C(23)H(24)N(2)O(5), the dihydro-furan ring adopts a twist conformation, while the piperidine ring is in a chair conformation. The benzene-fused cyclo-hexene ring adopts an envelope conformation. An intra-molecular C-H?O hydrogen bond is observed. Inter-molecular C-H?N and C-H?O hydrogen bonds form C(5) chains along the a and b axes, respectively, and together they form a three-dimensional network.

SUBMITTER: Odabasoglu M

PROVIDER: S-EPMC2970118 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

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N-Cyano-7α-methoxy-carbonyl-6,14-endo-ethenotetra-hydro-northebaine.

Odabaşoğlu Mustafa M Yavuz Serkan S Pamir Ozgür O Büyükgüngör Orhan O Yıldırır Yılmaz Y

Acta crystallographica. Section E, Structure reports online 20090822 Pt 9

<h4>In the title compound (systematic name</h4>methyl 17-cyano-3,6-dimeth-oxy-4,5α-ep-oxy-6,14-endo-ethenomorphinan-7-carboxyl-ate), C(23)H(24)N(2)O(5), the dihydro-furan ring adopts a twist conformation, while the piperidine ring is in a chair conformation. The benzene-fused cyclo-hexene ring adopts an envelope conformation. An intra-molecular C-H⋯O hydrogen bond is observed. Inter-molecular C-H⋯N and C-H⋯O hydrogen bonds form C(5) chains along the a and b axes, respectively, and together they ...[more]

PMID: 21577607

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