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1,3,5-Tris(N-phenyl-benzimidazol-2-yl)benzene methanol solvate.

ABSTRACT: The main mol-ecule of the title compound, C(45)H(30)N(6)·CH(3)OH, has a non-planar core: the dihedral angles between the benzimidazole rings and the central benzene ring are 20.19?(10), 34.57?(8), and 44.59?(8)°, while the dihedral angles between the peripheral phenyl rings and the attached benzimidazole rings are 84.57?(7), 62.71?(6) and 51.73?(6)°. The tri-substituted benzene mol-ecule is connected to the methanol solvent mol-ecule through an O-H?N hydrogen bond, forming a 1:1 solvate. In the crystal structure, no significant ?-? inter-actions are present, and the mol-ecules are associated through weak C-H?N and C-H?O(methanol) contacts.

SUBMITTER: Song WF

PROVIDER: S-EPMC2970194 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

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1,3,5-Tris(N-phenyl-benzimidazol-2-yl)benzene methanol solvate.

Song Wei-Feng WF Wu Ying Y Fan Yan Y Wang Yue Y Liu Yu Y

Acta crystallographica. Section E, Structure reports online 20090912 Pt 10

The main mol-ecule of the title compound, C(45)H(30)N(6)·CH(3)OH, has a non-planar core: the dihedral angles between the benzimidazole rings and the central benzene ring are 20.19 (10), 34.57 (8), and 44.59 (8)°, while the dihedral angles between the peripheral phenyl rings and the attached benzimidazole rings are 84.57 (7), 62.71 (6) and 51.73 (6)°. The tri-substituted benzene mol-ecule is connected to the methanol solvent mol-ecule through an O-H⋯N hydrogen bond, forming a 1:1 solvate. In the ...[more]

PMID: 21577916

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