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2-Cyano-anilinium dihydrogen phosphate.

ABSTRACT: In the cation of the title compound, C(7)H(7)N(2) (+)·H(2)PO(4) (-), the nitrile group and the benzene ring are almost coplanar (r.m.s. deviation = 0.0035?Å). The cations and anions are connected by inter-molecular N-H?O, O-H?O and O-H?N hydrogen bonds, together with ?-? inter-actions [centroid-centroid distance = 3.8131?(9)?Å], forming a three-dimensional network.

SUBMITTER: Zhang L

PROVIDER: S-EPMC2970356 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

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2-Cyano-anilinium dihydrogen phosphate.

Zhang Li L

Acta crystallographica. Section E, Structure reports online 20090912 Pt 10

In the cation of the title compound, C(7)H(7)N(2) (+)·H(2)PO(4) (-), the nitrile group and the benzene ring are almost coplanar (r.m.s. deviation = 0.0035 Å). The cations and anions are connected by inter-molecular N-H⋯O, O-H⋯O and O-H⋯N hydrogen bonds, together with π-π inter-actions [centroid-centroid distance = 3.8131 (9) Å], forming a three-dimensional network. ...[more]

PMID: 21577904

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