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4-Cyano-anilinium bromide.


ABSTRACT: In the crystal structure of the title compound, C(7)H(7)N(2) (+)·Br(-), the cations are associated into inversion dimers through weak pairwise C-H?N hydrogen bonds. The dimers further form stepped sheets via weak pairwise C-H?N hydrogen bonds. In the sheets, the spacing between the mean planes of the laterally displaced aromatic rings in adjacent dimers is 1.124?(6)?Å. Three N-H?Br inter-actions and two weak C-H?Br inter-actions per cation tie the sheets together.

SUBMITTER: Vumbaco DJ 

PROVIDER: S-EPMC3470237 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

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4-Cyano-anilinium bromide.

Vumbaco David J DJ   Kammer Michael N MN   Koplitz Lynn V LV   Mague Joel T JT  

Acta crystallographica. Section E, Structure reports online 20120908 Pt 10


In the crystal structure of the title compound, C(7)H(7)N(2) (+)·Br(-), the cations are associated into inversion dimers through weak pairwise C-H⋯N hydrogen bonds. The dimers further form stepped sheets via weak pairwise C-H⋯N hydrogen bonds. In the sheets, the spacing between the mean planes of the laterally displaced aromatic rings in adjacent dimers is 1.124 (6) Å. Three N-H⋯Br inter-actions and two weak C-H⋯Br inter-actions per cation tie the sheets together. ...[more]

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