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3-Benzyl-7-meth-oxy-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexa-hydro-1H-pyrrolo[3,4-b]quinoline.

ABSTRACT: In the title compound, C(32)H(32)N(2)O(3)S, the pyrrolidine ring adopts an envelope conformation with the methine C atom nearest to the phenyl ring as the flap atom. The tetra-hydro-pyridine ring has a half-chair conformation. The two rings are trans-fused. The phenyl ring bound to the tetra-hydro-pyridine is oriented almost perpendicular [dihedral angle = 86.35?(10)°] to the fused benzene ring. The dihedral angle between the benzyl-phenyl ring and the sulfonyl-bound phenyl ring is 69.43?(10)°. A very weak N-H?? inter-action is observed in the mol-ecular structure. In the crystal, mol-ecules translated one unit along the b axis are linked into C(10) chains by C-H?O hydrogen bonds; adjacent chains are linked via C-H?? inter-actions, forming a two-dimensional network parallel to the bc plane.

SUBMITTER: Chinnakali K

PROVIDER: S-EPMC2971011 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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3-Benzyl-7-meth-oxy-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexa-hydro-1H-pyrrolo[3,4-b]quinoline.

Chinnakali K K Sudha D D Jayagobi M M Raghunathan R R Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20091031 Pt 11

In the title compound, C(32)H(32)N(2)O(3)S, the pyrrolidine ring adopts an envelope conformation with the methine C atom nearest to the phenyl ring as the flap atom. The tetra-hydro-pyridine ring has a half-chair conformation. The two rings are trans-fused. The phenyl ring bound to the tetra-hydro-pyridine is oriented almost perpendicular [dihedral angle = 86.35 (10)°] to the fused benzene ring. The dihedral angle between the benzyl-phenyl ring and the sulfonyl-bound phenyl ring is 69.43 (10)°. ...[more]

PMID: 21578528

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