3-Benzyl-7-bromo-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexa-hydro-1H-pyrrolo[3,4-b]quinoline.
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ABSTRACT: In the title compound, C(31)H(29)BrN(2)O(2)S, the pyrrolidine ring is in a twist conformation and the tetra-hydro-pyridine ring adopts an envelope conformation with the methine C atom adjacent to the NH group as the flap atom; the two rings are trans-fused. The bromo-benzene ring and the nearest phenyl ring form a dihedral angle of 82.72 (10)°. The benzyl phenyl and the tosyl phenyl rings are oriented at a dihedral angle of 75.57 (11)°. An intra-molecular N-H⋯π inter-action is observed. In the crystal, mol-ecules are linked into chains running along [101] by C-H⋯O hydrogen bonds and the chains are cross-linked via weak C-H⋯π inter-actions.
SUBMITTER: Chinnakali K
PROVIDER: S-EPMC2971917 | biostudies-literature |
REPOSITORIES: biostudies-literature
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