Unknown

Dataset Information

0

2-Hydroxy-benzyl alcohol-phenanthroline (1/1).

ABSTRACT: Crystals of the title compound, C(12)H(8)N(2)·C(7)H(8)O(2), were obtained during cocrystallization experiments of a compound with two hydrogen-bond donors (2-hydroxy-benzyl alcohol) with another compound containing two hydrogen-bond acceptors (phenanthroline). Unexpectedly, the two mol-ecules do not form dimers with two O-H?N hydrogen bonds connecting the two mol-ecules. However, one of the hydr-oxy groups forms a bifurcated hydrogen bond to both phenanthroline N atoms, whereas the other hydr-oxy group forms an O-H?O hydrogen bond to a symmetry-equivalent 2-hydroxy-benzyl alcohol mol-ecule. In addition, the crystal packing is stabilized by ?-? inter-actions between the two phenanthroline ring systems, with a centroid-centroid distance of 3.570 ?Å.

SUBMITTER: Ton CQ 

PROVIDER: S-EPMC2971015 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

2-Hydroxy-benzyl alcohol-phenanthroline (1/1).

Ton Cuong Quoc CQ   Bolte Michael M  

Acta crystallographica. Section E, Structure reports online 20091031 Pt 11

Crystals of the title compound, C(12)H(8)N(2)·C(7)H(8)O(2), were obtained during cocrystallization experiments of a compound with two hydrogen-bond donors (2-hydroxy-benzyl alcohol) with another compound containing two hydrogen-bond acceptors (phenanthroline). Unexpectedly, the two mol-ecules do not form dimers with two O-H⋯N hydrogen bonds connecting the two mol-ecules. However, one of the hydr-oxy groups forms a bifurcated hydrogen bond to both phenanthroline N atoms, whereas the other hydr-ox  ...[more]

Similar Datasets

Unknown Dichlorido[N'-(3,5-dichloro-2-hydroxy-benzyl-idene)pyridine-4-carbohydrazide-?N](1,10-phenanthroline-?N,N')cobalt(II) methanol monosolvate.
| S-EPMC2972077 | biostudies-literature
Unknown N-Benzyl-2-hydroxy-benzamide.
| S-EPMC2961206 | biostudies-literature
Unknown N'-(5-Bromo-2-hydroxy-benzyl-idene)-3-hydroxy-benzohydrazide.
| S-EPMC2960470 | biostudies-literature
Unknown N'-(5-Chloro-2-hydroxy-benzyl-idene)-4-hydroxy-benzohydrazide.
| S-EPMC2977672 | biostudies-literature
Unknown 2-(2-Hydroxy-benzyl-ideneamino)benzonitrile.
| S-EPMC2961580 | biostudies-literature
Unknown 3-(2-Hydroxy-benzyl-ideneamino)benzonitrile.
| S-EPMC2960747 | biostudies-literature
Unknown 4-(2-Hydroxy-benzyl-idene-amino)-benzonitrile.
| S-EPMC2961783 | biostudies-literature
Unknown N'-(3-Bromo-5-chloro-2-hydroxy-benzyl-idine)-2-hydroxy-benzohydrazide.
| S-EPMC2959983 | biostudies-literature
Unknown (E)-N'-(3,5-Dibromo-2-hydroxy-benzyl-idene)-4-hydroxy-benzohydrazide monohydrate.
| S-EPMC2959471 | biostudies-literature
Unknown N'-(3-Eth-oxy-2-hydroxy-benzyl-idene)-3-hydroxy-naphthalene-2-carbohydrazide.
| S-EPMC2961181 | biostudies-literature