Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Dichlorido[N'-(3,5-dichloro-2-hydroxy-benzyl-idene)pyridine-4-carbohydrazide-?N](1,10-phenanthroline-?N,N')cobalt(II) methanol monosolvate.

ABSTRACT: In the title compound, [CoCl(2)(C(13)H(9)Cl(2)N(3)O(2))(2)(C(12)H(8)N(2))]·CH(3)OH, the Co(II) atom is octahedrally coordinated by two N atoms from the pyridyl rings of the tridentate N'-(3,5-dichloro-2-hydroxy-benzyl-idene)pyridine-4-carbohydrazide (H(2)L) ligand, two N atoms from the 1,10-phenanthroline ligand and two chloride ions. The acyl-hydrazone groups are not involved into the coordination of the metal ion. In the crystal packing an extended three-dimensional network formed by N-H?Cl, N-H?O, O-H?N, O-H?N and O-H?Cl hydrogen bonds is observed.

SUBMITTER: Wang Y

PROVIDER: S-EPMC2972077 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Dichlorido[N'-(3,5-dichloro-2-hydroxy-benzyl-idene)pyridine-4-carbohydrazide-κN](1,10-phenanthroline-κN,N')cobalt(II) methanol monosolvate.

Wang Yuan Y Liu Zheng Z Liu Baoyu B

Acta crystallographica. Section E, Structure reports online 20091118 Pt 12

In the title compound, [CoCl(2)(C(13)H(9)Cl(2)N(3)O(2))(2)(C(12)H(8)N(2))]·CH(3)OH, the Co(II) atom is octahedrally coordinated by two N atoms from the pyridyl rings of the tridentate N'-(3,5-dichloro-2-hydroxy-benzyl-idene)pyridine-4-carbohydrazide (H(2)L) ligand, two N atoms from the 1,10-phenanthroline ligand and two chloride ions. The acyl-hydrazone groups are not involved into the coordination of the metal ion. In the crystal packing an extended three-dimensional network formed by N-H⋯Cl, N ...[more]

PMID: 21578623

Similar Datasets

mer-(3,5-Dichloro-2-oxidobenzaldehyde thio-semicarbazonato-κS,N,O)(methanol-κO)(1,10-phenanthroline-κN,N')nickel(II).

Project description:In the title compound, [Ni(C(8)H(5)Cl(2)N(3)OS)(C(12)H(8)N(2))(CH(3)OH)], the Ni(II) atom is octa-hedrally coordinated by one N, one O and one S atom from a 3,5-dichloro-2-oxidobenzaldehyde thio-semicarbazonate ligand, another O atom from methanol and another two N atoms from 1,10-phenanthroline. The crystal structure is constructed by N-H⋯Cl, N-H⋯N, C-H⋯S and O-H⋯S hydrogen bonds.

| S-EPMC2977580 | biostudies-literature

2,9-Dichloro-1,10-phenanthroline.

Project description:The title mol-ecule, C(12)H(6)Cl(2)N(2), is almost planar (the r.m.s. deviation of C atoms is 0.04 Å). The C-N and C-C distances indicate delocalization of the π-electrons in the aromatic fused-ring system.

| S-EPMC2969030 | biostudies-literature

Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-?N,N')cobalt(II) dichloro-methane hemisolvate.

Project description:The title compound, [CoCl(2)(C(21)H(17)ClN(2))]·0.5CH(2)Cl(2), crystallizes from dichloro-methane as a 2:1 solvate [CoCl(2)L](2)·CH(2)Cl(2) (L is 2-chloro-9-mesityl-1,10-phenanthroline). There are two independent CoCl(2)L mol-ecules in the asymmetric unit and both mol-ecules have similar conformations. They are connected by a weak C-H?? inter-action involving the mesityl ring. The cobalt center is four-coordinated by the two N-atom donors of the bidentate ligand and two chloride ions in a distorted tetra-hedral geometry. The packing of the mol-ecules is stabilized by weak slipped ?-? stacking inter-actions between symmetry-related phenanthroline groups.

| S-EPMC2961318 | biostudies-literature

Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-?N)-1,10-phenanthroline-?N,N']cadmium(II).

Project description:The asymmetric unit of the title compound, [CdCl(2)(C(17)H(14)N(4))], contains two independent mol-ecules in which the Cd(II) ions are in distorted trigonal-bipyramidal CdN(3)Cl(2) coordination environments. In the crystal structure, there is a ?-? stacking inter-action involving a pyridine ring and a symmetry-related benzene ring, with a centroid-centroid distance of 3.5088?(19)?Å.

| S-EPMC2979538 | biostudies-literature

Dichlorido(methanol-κO)[2-(2-pyridyl-meth-oxy)-1,10-phenanthroline-κN,N',N'']manganese(II).

Project description:In the title mononuclear complex, [MnCl(2)(C(18)H(13)N(3)O)(CH(4)O)], the Mn(II) ion assumes a distorted octa-hedral geometry. There is a π-π stacking inter-action between the phenanthroline ligand and the pyridine ring of a neighboring complex [centroid-to-centroid distance 3.5518 (13) Å]. The crystal structure also contains weak inter-molecular O-H⋯Cl hydrogen bonds that link neighboring complex mol-ecules into a one-dimensional chain along the b axis.

| S-EPMC2961758 | biostudies-literature

N'-(3,5-Dichloro-2-hydroxy-benzyl-idene)-3-methoxy-benzohydrazide methanol solvate.

Project description:In the title compound, C(15)H(12)Cl(2)N(2)O(3)·CH(3)OH, the Schiff base mol-ecule is nearly planar, with a dihedral angle of 4.5 (2)° between the two benzene rings. An intra-molecular O-H⋯N hydrogen bond is observed. The methanol solvent mol-ecule is linked to the Schiff base mol-ecule through inter-molecular N-H⋯O and O-H⋯O hydrogen bonds.

| S-EPMC2961072 | biostudies-literature

Dichlorido(1,10-phenanthroline-?N,N')palladium(II).

Project description:In the title complex, [PdCl(2)(C(12)H(8)N(2))], the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two chloride ions. The nearly planar mol-ecules, with a maximum deviation of 0.120?(3)?Å from the least-squares plane, are stacked in columns along the c axis with a Pd?Pd distance of 4.8340?(9)?Å. In the column, ?-? inter-actions between adjacent six-membered rings are present, the shortest centroid-centroid distance being 3.680?(4)?Å. A weak C-H?Cl inter-action is observed between the columns.

| S-EPMC2980155 | biostudies-literature

Bis(N'-benzoyl-pyridine-4-carbohydrazide)(1,10-phenanthroline)copper(II) dinitrate.

Project description:In the title complex, [Cu(C(13)H(11)N(3)O(2))(2)(C(12)H(8)N(2))](NO(3))(2), the Cu(II )atom (site symmetry 2) is coordinated by four N atoms from one 1,10-phenanthroline and two hydrazine ligands, respectively. The hydrazine ligands coordinate to the Cu(II)atom by a pyridine N atom. These four atoms form a slightly distorted square-planar N(4) donor set. In the packing, two additional Cu?O inter-actions occur [Cu?O = 2.462?(2)?Å], resulting in a typical Jahn-Teller-distorted octahedral environment around the Cu atom. N-H?O hydrogen bonds result in a three-dimensional network. The O atoms of the anion are disordered over two positions in a 0.68?(2):0.32?(2) ratio.

| S-EPMC3009134 | biostudies-other

1,10-Phenanthroline-5,6-dione ethanol monosolvate.

Project description:In the title compound, C12H6N2O2·C2H5OH, the mol-ecule of the 1,10-phenanthroline-5,6-dione is approximately planar, with a maximum deviation of 0.051?(1)?Å. In the crystal, mol-ecules are linked by O-H?N and weak C-H?O hydrogen bonds, forming supra-molecular chains propagating along [110]. ?-? stacking inter-actions are observed between the pyridine rings of neighbouring chains, the centroid-centroid separations being 3.6226?(11) and 3.7543?(11)?Å.

| S-EPMC4011276 | biostudies-literature

(2,9-Dimethyl-1,10-phenanthroline)(4-hydroxy-pyridine-2,6-dicarboxyl-ato)copper(II) trihydrate.

Project description:In the title complex, [Cu(C(7)H(3)NO(5))(C(14)H(12)N(2))]·3H(2)O, there are two independent neutral mol-ecules of the Cu complex along with six mol-ecules of water of hydration in the asymmetric unit. The Cu(II )atoms in each complex adopt a distorted square-pyramidal coordination geometry being penta-coordinated by one N and two O atoms of 4-hydroxy-pyridine-2,6-dicarboxyl-ate anions and two N atoms of 2,9-dimethyl-1,10-phenanthroline (dmp) molecules. In the crystal structure, there are O-H?O and C-H?O hydrogen bonds and five ?-? stacking inter-actions with centroid-centroid distances in the range 3.620?(1)-3.712?(1)?Å. In addition, a C-H?? inter-action between a heterocyclic ring of dmp is observed to reinforce the crystal cohesion.

| S-EPMC2969473 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data