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N-(4-Methoxy-phen-yl)-tert-butane-sulfinamide.

ABSTRACT: In the title compound, C(11)H(17)NO(2)S, the mol-ecules inter-act head-to-tail through N-H?OS hydrogen bonds, giving discrete centrosymmetric cyclic dimers. The N-C(ar-yl) bond length [1.4225?(14)?Å] is inter-mediate between that in N-phenyl-tert-butane-sulfinamide [1.4083?(12)?Å] and the N-C(alk-yl) bond lengths in N-alkyl-alkanesulfinamides (1.470-1.530?Å), suggesting weaker delocalization of electrons over the N atom and the aromatic ring due to the presence of the 4-meth-oxy group.

SUBMITTER: Datta M 

PROVIDER: S-EPMC2971111 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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N-(4-Methoxy-phen-yl)-tert-butane-sulfinamide.

Datta Mrityunjoy M   Buglass Alan J AJ   Elsegood Mark R J MR  

Acta crystallographica. Section E, Structure reports online 20091023 Pt 11

In the title compound, C(11)H(17)NO(2)S, the mol-ecules inter-act head-to-tail through N-H⋯OS hydrogen bonds, giving discrete centrosymmetric cyclic dimers. The N-C(ar-yl) bond length [1.4225 (14) Å] is inter-mediate between that in N-phenyl-tert-butane-sulfinamide [1.4083 (12) Å] and the N-C(alk-yl) bond lengths in N-alkyl-alkanesulfinamides (1.470-1.530 Å), suggesting weaker delocalization of electrons over the N atom and the aromatic ring due to the presence of the 4-meth-oxy group. ...[more]

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