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(5Z)-5-(2-Methyl-benzyl-idene)-3-phenyl-2-thioxo-1,3-thia-zolidin-4-one.

ABSTRACT: In the title compound, C(17)H(13)NOS(2), the heterocyclic ring is oriented at a dihedral angle of 74.43?(5)° with respect to the anilinic benzene ring and at a dihedral angle of 17.31?(9)° with respect to phenyl ring. An intra-molecular C-H?S inter-action occurs, resulting in an S(6) ring. In the crystal, the packing is consolidated by C-H?? inter-actions and possible very weak aromatic ?-? stacking [centroid-centroid separation = 4.025?(1)?Å].

SUBMITTER: Shahwar D

PROVIDER: S-EPMC2971373 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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(5Z)-5-(2-Methyl-benzyl-idene)-3-phenyl-2-thioxo-1,3-thia-zolidin-4-one.

Shahwar Durre D Tahir M Nawaz MN Raza Muhammad Asam MA Iqbal Bushra B

Acta crystallographica. Section E, Structure reports online 20091031 Pt 11

In the title compound, C(17)H(13)NOS(2), the heterocyclic ring is oriented at a dihedral angle of 74.43 (5)° with respect to the anilinic benzene ring and at a dihedral angle of 17.31 (9)° with respect to phenyl ring. An intra-molecular C-H⋯S inter-action occurs, resulting in an S(6) ring. In the crystal, the packing is consolidated by C-H⋯π inter-actions and possible very weak aromatic π-π stacking [centroid-centroid separation = 4.025 (1) Å]. ...[more]

PMID: 21578495

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