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(5Z)-5-(2-Hy-droxy-benzyl-idene)-3-(4-methyl-phen-yl)-2-sulfanyl-idene-1,3-thia-zolidin-4-one.

ABSTRACT: In the title compound, C(17)H(13)NO(2)S(2), the dihedral angles between the 2-sulfanyl-idene-1,3-thia-zolidin-4-one group and the pendant toluene and 2-hy-droxy-benzene rings are 74.62?(6) and 8.73?(12)°, respectively. An intra-molecular C-H?S inter-action occurs. In the crystal, inversion dimers linked by pairs of O-H?O hydrogen bonds generate R(2) (2)(16) loops. This link is reinforced by a pair of C-H?O hydrogen bonds. The dimers are connected by weak C-H?S inter-actions.

SUBMITTER: Shahwar D

PROVIDER: S-EPMC3379392 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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(5Z)-5-(2-Hy-droxy-benzyl-idene)-3-(4-methyl-phen-yl)-2-sulfanyl-idene-1,3-thia-zolidin-4-one.

Shahwar Durre D Tahir M Nawaz MN Kashif Misbah M Saeed Afifa A Bukhari Sana S

Acta crystallographica. Section E, Structure reports online 20120519 Pt 6

In the title compound, C(17)H(13)NO(2)S(2), the dihedral angles between the 2-sulfanyl-idene-1,3-thia-zolidin-4-one group and the pendant toluene and 2-hy-droxy-benzene rings are 74.62 (6) and 8.73 (12)°, respectively. An intra-molecular C-H⋯S inter-action occurs. In the crystal, inversion dimers linked by pairs of O-H⋯O hydrogen bonds generate R(2) (2)(16) loops. This link is reinforced by a pair of C-H⋯O hydrogen bonds. The dimers are connected by weak C-H⋯S inter-actions. ...[more]

PMID: 22719590

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