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Trans-Dichloridotetrakis-[1-(2-hydroxy-ethyl)-1H-tetrazole-?N]cobalt(II).

ABSTRACT: The title cobalt(II) complex, [CoCl(2)(C(3)H(6)N(4)O)(4)], was obtained from metallic cobalt by direct synthesis. There are two Co atoms in the asymmetric unit, each lying on an inversion centre and adopting a distorted octa-hedral coordination. Classical and non-classical hydrogen bonds are responsible for formation of a three-dimensional polymeric network in the crystal.

SUBMITTER: Lyakhov AS

PROVIDER: S-EPMC2971423 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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trans-Dichloridotetrakis-[1-(2-hydroxy-ethyl)-1H-tetrazole-κN]cobalt(II).

Lyakhov Alexander S AS Mosalkova Anastasiya P AP Degtyarik Mikhail M MM Ivashkevich Ludmila S LS Gaponik Pavel N PN

Acta crystallographica. Section E, Structure reports online 20091023 Pt 11

The title cobalt(II) complex, [CoCl(2)(C(3)H(6)N(4)O)(4)], was obtained from metallic cobalt by direct synthesis. There are two Co atoms in the asymmetric unit, each lying on an inversion centre and adopting a distorted octa-hedral coordination. Classical and non-classical hydrogen bonds are responsible for formation of a three-dimensional polymeric network in the crystal. ...[more]

PMID: 21578141

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