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Bis[N,N-bis-(2-hydroxy-ethyl)dithio-carbamato-κS,S']copper(II).

ABSTRACT: In the title compound, [Cu(C(5)H(10)NO(2)S(2))(2)], the Cu(II) cation is chelated by two bis-(2-hydroxy-ethyl)dithio-carbamate anions with a distorted square-planar coordination geometry. Inter-molecular O-H⋯O hydrogen bonding is observed between the terminal hydr-oxy groups in the crystal structure.

SUBMITTER: Hou LF

PROVIDER: S-EPMC2971934 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Bis(N-butyl-N-ethyl-dithio-carbamato-κS,S')nickel(II).

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Bis(μ-N-benzyl-N-tetra-decyl-dithio-carbamato-κS:S')bis-[(N-benzyl-N-tetra-decyl-dithio-carbamato-κS,S')zinc(II)].

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Bis(?-N,N-dimethyl-dithio-carbamato-?S,S':S)bis-[(N,N-dimethyl-dithio-carbamato-?S,S')copper(II)].

Project description:In the centrosymmetric dimeric title compound, [Cu(2)(C(3)H(6)NS(2))(4)], the Cu(II) atom is five-coordinate in a square-pyramidal environment. The basal coordination positions are occupied by four S atoms from two dimethyl-dithio-carbamate ligands and the apical coordination position is occupied by an S atom also bonded to the other Cu atom.

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μ-1,2-Di-4-pyridylethane-κN:N'-bis-[bis-(N,N-diisopropyl-dithio-carbamato-κS,S')zinc(II)].

Project description:In the dinuclear title compound, [Zn{S(2)CN(n-Pr)(2)}(2){(NC(5)H(4))CH(2)CH(2)(C(5)H(4)N)}] or [Zn(2)(C(7)H(14)NS(2))(4)(C(12)H(12)N(2))], each Zn atom adopts a distorted trigonal-bipyramidal ZnNS(4) geometry. The crystal structure involves intermolecular C-H⋯S hydrogen bonds.

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Project description:The title compound, [Cd(C(5)H(10)NO(2)S(2))(2)(C(10)H(8)N(2))], features a trigonal-prismatic coordination geometry for the Cd(II) ion, based on an N(2)S(4) donor set defined by two chelating dithio-carbamate ligands and a 2,2'-bipyridyl ligand. In the crystal, extensive O-H?O hydrogen bonding results in the formation of 12-membered {?HO}(6) synthons and one-dimensional supra-molecular chains with further O-H?S inter-actions providing additional stability to the linear chain with base vector [01].

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Bis(N-sec-butyl-N-n-propyl-dithio-carbamato-κS,S')(1,10-phenanthroline-κN,N')zinc(II).

Project description:Two independent but very similar mol-ecules comprise the asymmetric unit of the title compound, [Zn(C(8)H(16)NS(2))(2)(C(12)H(8)N(2))]. The N(2)S(4) donor set about Zn is defined by two symmetrically chelating dithio-carbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octa-hedral coordination geometry arise from the restricted bite angles of the ligands. The main feature of the crystal packing is the formation of tetra-meric supra-molecular aggregates mediated by C-H⋯S inter-actions. Disorder was found in each of the sec-butyl groups. This was resolved over two positions in each case with the major components of the disorder having site occupancies in the range 0.551 (6)-0.725 (5).

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