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Di-n-butyl-bis-(N-ethyl-N-phenyl-dithio-carbamato-κS)tin(IV).

ABSTRACT: The title compound, [Sn(C(4)H(9))(2)(C(9)H(10)NS(2))(2)], features a tetra-hedrally coordinated Sn(IV) atom; the dithio-carbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the Sn(IV) atom [3.0136 (7) and 2.9865 (8) Å], giving rise to distortions from the ideal geometry as evident in the wide C-Sn-C bond angle of 139.06 (12) °. In the crystal, C-H⋯S inter-actions lead to the formation of a linear supra-molecular chain along the b axis. The chains are aligned into layers by C-H⋯π inter-actions, and the layers stack along [001]. One of the ethyl groups is statistically disordered over two sets of sites.

SUBMITTER: Kamaludin NF 

PROVIDER: S-EPMC3254340 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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Di-n-butyl-bis-(N-ethyl-N-phenyl-dithio-carbamato-κS)tin(IV).

Kamaludin Nurul Farahana NF   Baba Ibrahim I   Awang Normah N   Mohamed Tahir Mohamed Ibrahim MI   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20111223 Pt 1

The title compound, [Sn(C(4)H(9))(2)(C(9)H(10)NS(2))(2)], features a tetra-hedrally coordinated Sn(IV) atom; the dithio-carbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the Sn(IV) atom [3.0136 (7) and 2.9865 (8) Å], giving rise to distortions from the ideal geometry as evident in the wide C-Sn-C bond angle of 139.06 (12) °. In the crystal, C-H⋯S inter-actions lead to the formation of a linear supra  ...[more]

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