Browse
Submit Data
Databases
API
Help

Dataset Information

27 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(m-Phenyl-enedimethyl-ene)bis-(triphenyl-phospho-nium) bis-[chlorido(penta-fluoro-phen-yl)aurate(I)] dichloro-methane disolvate.

ABSTRACT: The title compound, (C(44)H(38)P(2))[AuCl(C(6)F(5))](2)·2CH(2)Cl(2), crystallizes with a twofold rotation axis through the central benzene ring in the bis-phospho-nium dication. In the crystal, the dications and anions are ordered into columns running parallel to the c axis by contacts of the pro-ylidic CH(2) groups with the Cl atom of one and an ortho-F atom of another anion. The space between the columns is occupied by CH(2)Cl(2) solvent mol-ecules.

SUBMITTER: Strasser CE

PROVIDER: S-EPMC2971990 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

?-Oxalato-bis-[bis-(triphenyl-phosphine)copper(I)] dichloro-methane disolvate.

Project description:The dinuclear molecule of the title compound, [Cu(2)(C(2)O(4))(C(18)H(15)P)(4)]·2CH(2)Cl(2), lies across an inversion center with a strictly planar bridging oxalate ligand coordinating two Cu(I) ions via two pairs of O atoms. Two triphenyl-phosphine ligands also coordinate each symmetry-related Cu(I) ion, resulting in a distorted tetra-hedral geometry [O-Cu-O = 80.57?(5)° and P-Cu-P = 125.72?(2)°]. In the crystal, there are two dichloro-methane solvent mol-ecules for each dinuclear complex.

| S-EPMC3569214 | biostudies-literature

Bis(tetra-phenyl-phospho-nium) tetra-chlorido-cobaltate(II).

Project description:The title compound, (C24H20P)2[CoCl4], was prepared under hydro-thermal conditions. In the crystal, the tetra-phenyl-phospho-nium cations are linked by pairs of weak C-H⋯π inter-actions into supra-molecular dimers; the Co(II) cations lie on twofold rotation axes and the tetra-hedral [CoCl4](2-) anions are linked with the tetra-phenyl-phospho-nium cations via weak C-H⋯Cl hydrogen bonds.

| S-EPMC4051096 | biostudies-literature

Benzyl-triphenyl-phospho-nium perchlorate.

Project description:The asymmetric unit of the title compound, C(25)H(22)P(+)·ClO(4) (-), contains two independent cations and two independent anions. The closest inter-molecular contact is a weak inter-molecular C-H??(arene) inter-action.

| S-EPMC3151880 | biostudies-literature

Benzyl-triphenyl-phospho-nium dichlorido-triphenyl-stannate(IV).

Project description:The crystal structure of the title salt, (C25H22P)[Sn(C6H5)3Cl2] or (PhCH2PPh3)[SnPh3Cl2], consists of [PhCH2PPh3](+) cations and [SnPh3Cl2](-) anions in which the Sn(IV) atom is linked to two Cl atoms and three phenyl groups in a trigonal-bipyramidal geometry, with the Cl atoms in trans positions. The cation adopts a tetra-hedral geometry. In the crystal, the cations and the anions are connected by C-H?Cl hydrogen bonds, leading to an infinite chain propagating along the c direction.

| S-EPMC3588253 | biostudies-literature

Bis[(4-chloro-benz-yl)triphenyl-phospho-nium] tetra-chloridozincate(II) trihydrate.

Project description:The crystal structure of the title compound, (C(25)H(21)ClP)(2)[ZnCl(4)]·3H(2)O, consists of tetra-hedral phosphonium cations and tetra-hedral zincate anions; the water mol-ecules form weak hydrogen bonds to the anions. Two of the water mol-ecules are disordered over three sites in a 0.68:0.55:0.77 ratio.

| S-EPMC2979374 | biostudies-literature

Ethyl-triphenyl-phospho-nium bromide dihydrate.

Project description:In the crystal structure of the title hydrated bromide salt, C(20)H(20)P(+)·Br(-)·2H(2)O, O-H?Br and O-H?O hydrogen bonds as well as C-H?Br contacts connect the different components into a three-dimensional network. In the cation, the aromatic rings make dihedral angles of 55.24?(5), 76.16?(4) and 85.68?(4)°.

| S-EPMC3212335 | biostudies-literature

Isopropyl-triphenyl-phospho-nium bromide monohydrate.

Project description:In the title water-solvated salt, C(21)H(22)P(+)·Br(-)·H(2)O, the ionic components are linked by short C-H⋯Br contacts along the a-axis direction. The two half occupied water mol-ecules are connected to each other by strong O-H⋯O hydrogen bonds and they are also linked to the bromide anion by short O-H⋯Br contacts.

| S-EPMC3238822 | biostudies-literature

Bis(isopropyl-triphenyl-phospho-nium) di-?-iodido-bis-[iodidocopper(I)].

Project description:The title compound, (C(21)H(22)P)(2)[Cu(2)I(4)], prepared from reaction between copper powder, iodine and isopropyl triphenyl-phospho-nium iodide in hydroxy-acetone (acetol), shows an already known Cu(2)I(4) (2-) anion with a planar conformation [Cu-I range = 2.5108?(3)-2.5844?(3)?Å and I-Cu-I range = 110.821?(10)-125.401?(10)°].

| S-EPMC2984081 | biostudies-other

Dicyclo-hexyl-bis-(naphthalen-1-ylmeth-yl)phospho-nium chloride chloro-form disolvate.

Project description:In the title solvated phosphonium salt, C34H40P(+)·Cl(-)·2CHCl3, the two cyclo-hexyl and two 1-naphthyl-methyl groups at the P atom are in a distorted tetra-hedral arrangement [105.26 (6)-113.35 (6)°]. Both cyclo-hexyl rings adopt a chair conformation. The dihedral angle between the naphthyl ring systems is 74.08 (3)°.

| S-EPMC3588969 | biostudies-literature

(Cyano-meth-yl)triphenyl-phospho-nium chloride.

Project description:In the mol-ecule of the title compound, C(20)H(17)NP(+)·Cl(-), the coordination around the P atom is slightly distorted tetra-hedral. In the crystal structure, inter-molecular C-H⋯N and C-H⋯Cl hydrogen bonds link the mol-ecules. There is a π-π contact between the phenyl rings [centroid-centroid distance = 3.702 (3) Å].

| S-EPMC2959552 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data