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(m-Phenyl-enedimethyl-ene)bis-(triphenyl-phospho-nium) bis-[chlorido(penta-fluoro-phen-yl)aurate(I)] dichloro-methane disolvate.

ABSTRACT: The title compound, (C(44)H(38)P(2))[AuCl(C(6)F(5))](2)·2CH(2)Cl(2), crystallizes with a twofold rotation axis through the central benzene ring in the bis-phospho-nium dication. In the crystal, the dications and anions are ordered into columns running parallel to the c axis by contacts of the pro-ylidic CH(2) groups with the Cl atom of one and an ortho-F atom of another anion. The space between the columns is occupied by CH(2)Cl(2) solvent mol-ecules.

SUBMITTER: Strasser CE 

PROVIDER: S-EPMC2971990 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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(m-Phenyl-enedimethyl-ene)bis-(triphenyl-phospho-nium) bis-[chlorido(penta-fluoro-phen-yl)aurate(I)] dichloro-methane disolvate.

Strasser Christoph E CE   Coetzee Karolien K   Cronje Stephanie S   Raubenheimer Helgard G HG  

Acta crystallographica. Section E, Structure reports online 20091104 Pt 12

The title compound, (C(44)H(38)P(2))[AuCl(C(6)F(5))](2)·2CH(2)Cl(2), crystallizes with a twofold rotation axis through the central benzene ring in the bis-phospho-nium dication. In the crystal, the dications and anions are ordered into columns running parallel to the c axis by contacts of the pro-ylidic CH(2) groups with the Cl atom of one and an ortho-F atom of another anion. The space between the columns is occupied by CH(2)Cl(2) solvent mol-ecules. ...[more]

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