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Benzyl-triphenyl-phospho-nium dichlorido-triphenyl-stannate(IV).

ABSTRACT: The crystal structure of the title salt, (C25H22P)[Sn(C6H5)3Cl2] or (PhCH2PPh3)[SnPh3Cl2], consists of [PhCH2PPh3](+) cations and [SnPh3Cl2](-) anions in which the Sn(IV) atom is linked to two Cl atoms and three phenyl groups in a trigonal-bipyramidal geometry, with the Cl atoms in trans positions. The cation adopts a tetra-hedral geometry. In the crystal, the cations and the anions are connected by C-H?Cl hydrogen bonds, leading to an infinite chain propagating along the c direction.

SUBMITTER: Traore B 

PROVIDER: S-EPMC3588253 | biostudies-literature | 2013 Jan

REPOSITORIES: biostudies-literature

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Benzyl-triphenyl-phospho-nium dichlorido-triphenyl-stannate(IV).

Traore Bocar B   Boye Mouhamadou Sembene MS   Sidibe Mamadou M   Diop Libasse L   Guionneau Philippe P  

Acta crystallographica. Section E, Structure reports online 20121212 Pt 1

The crystal structure of the title salt, (C25H22P)[Sn(C6H5)3Cl2] or (PhCH2PPh3)[SnPh3Cl2], consists of [PhCH2PPh3](+) cations and [SnPh3Cl2](-) anions in which the Sn(IV) atom is linked to two Cl atoms and three phenyl groups in a trigonal-bipyramidal geometry, with the Cl atoms in trans positions. The cation adopts a tetra-hedral geometry. In the crystal, the cations and the anions are connected by C-H⋯Cl hydrogen bonds, leading to an infinite chain propagating along the c direction. ...[more]

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