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Poly[[?(2)-acetato-aquadi-?(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate].

ABSTRACT: In the title three-dimensional heterometallic complex, {[AgDy(C(6)H(4)NO(2))(2)(C(2)H(3)O(2))(H(2)O)]ClO(4)}(n), the Dy(III) ion is eight-coordinated by four O atoms from four different isonicotinate ligands, three O atoms from two different acetate ligands and one O atom of water mol-ecule. The two-coordinate Ag(I) ion is bonded to two N atoms from two different isonicotinate anions. These metal coordination units are connected by bridging isonicotinate and acetate ligands, generating a three-dimensional network. The coordinated water mol-ecules link the carboxyl-ate group and the acetate ligand by O-H?O hydrogen bonding. The perchlorate anion is disordered over two sites with site occupancy factors 0.508?(12) and 0.492?(12) and the methyl group of the acetate ligand is disordered over two positions of equal occupancy.

SUBMITTER: Zhu LC

PROVIDER: S-EPMC2972040 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate].

Zhu Li-Cai LC

Acta crystallographica. Section E, Structure reports online 20091118 Pt 12

In the title three-dimensional heterometallic complex, {[AgDy(C(6)H(4)NO(2))(2)(C(2)H(3)O(2))(H(2)O)]ClO(4)}(n), the Dy(III) ion is eight-coordinated by four O atoms from four different isonicotinate ligands, three O atoms from two different acetate ligands and one O atom of water mol-ecule. The two-coordinate Ag(I) ion is bonded to two N atoms from two different isonicotinate anions. These metal coordination units are connected by bridging isonicotinate and acetate ligands, generating a three-d ...[more]

PMID: 21578624

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