Unknown

Dataset Information

0

Poly[diethyl-enetriammonium [aquadi-?(2)-sulfato-sulfatocerium(III)]].

ABSTRACT: A new organically templated open-framework cerium sulfate, {(C(4)H(16)N(3))[Ce(SO(4))(3)(H(2)O)]}(n), was hydro-thermally synthesized. The Ce(III) cation is nine-coordinated by nine O atoms, including one water mol-ecule. Two of the SO(4) groups afford one monodentate and bidentate linkages as the bridge to connect adjacent Ce(III) cations, while the third SO(4) group attaches the Ce(III) cation in a bidentate mode. The crystal structure consists of layers composed of eight-membered-ring networks formed by four CeO(9) polyhedra and four SO(4) tetra-hedra. The triply protonated diethyl-enetriamine cations are located between adjacent layers and connect the layers via hydrogen bonds.

SUBMITTER: Zhang XM 

PROVIDER: S-EPMC2979358 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Poly[diethyl-enetriammonium [aquadi-μ(2)-sulfato-sulfatocerium(III)]].

Zhang Xiu-Mei XM   Li Ya-Feng YF  

Acta crystallographica. Section E, Structure reports online 20100515 Pt 6

A new organically templated open-framework cerium sulfate, {(C(4)H(16)N(3))[Ce(SO(4))(3)(H(2)O)]}(n), was hydro-thermally synthesized. The Ce(III) cation is nine-coordinated by nine O atoms, including one water mol-ecule. Two of the SO(4) groups afford one monodentate and bidentate linkages as the bridge to connect adjacent Ce(III) cations, while the third SO(4) group attaches the Ce(III) cation in a bidentate mode. The crystal structure consists of layers composed of eight-membered-ring network  ...[more]

Similar Datasets

Unknown Poly[diethyl-enetriammonium [aquadi-?(2)-sulfato-sulfatolanthanum(III)]].
| S-EPMC2969472 | biostudies-other
Unknown Poly[tetra-aquadi-?(4)-oxalato-lutetium(III)potassium].
| S-EPMC3247002 | biostudies-literature
Unknown Poly[tetra-aquadi-?(4)-oxalato-potassium-ytterbium(III)].
| S-EPMC3238636 | biostudies-literature
Unknown Poly[dimethyl-ammonium [aquadi-?(2)-oxalato-dysprosate(III)] trihydrate].
| S-EPMC3007264 | biostudies-literature
Unknown Poly[[tetra-aquadi-?(3)-oxalato-?(2)-oxalato-diprasedymium(III)] dihydrate].
| S-EPMC2980182 | biostudies-literature
Unknown Poly[dimethyl-ammonium [aquadi-μ(2)-oxalato-yttriate(III)] trihydrate].
| S-EPMC3151934 | biostudies-literature
Unknown Poly[[tetra-aquadi-?4-fumarato-?2-oxalato-dierbium(III)] tetra-hydrate].
| S-EPMC3588352 | biostudies-literature
Unknown Poly[[?(2)-acetato-aquadi-?(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate].
| S-EPMC2972040 | biostudies-literature
Unknown Crystal structure of poly[?6-adipato-di-aquadi-?2-oxalato-didysprosium(III)].
| S-EPMC4257430 | biostudies-literature
Unknown Poly[dimethyl-ammonium [aquadi-?(2)-oxalato-samarate(III)] trihydrate].
| S-EPMC3152119 | biostudies-other